Meteorology: The Science of the AtmosphereTalman, Charles Fitzhugh
Science
Meteorology: The Science of the Atmosphere
Talman, Charles Fitzhugh
Meteorology
When an inclosed body of air or other gas is subjected to pressure,
its volume is diminished and its density is increased. It is natural
to inquire what will happen if the external pressure be increased
indefinitely. Will the inclosed substance eventually cease to be
gaseous and become a solid or a liquid? The answer to this question,
furnished about half a century ago through the researches of Thomas
Andrews, is that no amount of pressure will liquefy a gas unless
its temperature is below a certain point. This point, known as the
_critical temperature_, is widely different for different substances.
For most of the atmospheric gases it is exceedingly low. Thus oxygen
must be cooled to 118° below zero Centigrade (180° below zero
Fahrenheit) before it will liquefy under any pressure, and the critical
temperature of nitrogen is still lower. Efforts to liquefy the gases
of the atmosphere were unsuccessful for a long time on account of the
difficulty of attaining such low temperatures.
Nowadays the problem is so completely solved that the manufacture
of liquid air is a commonplace commercial enterprise, and millions
of gallons are produced every year. Liquid air is the principal
commercial source of pure oxygen, nitrogen, and other gases found in
the atmosphere. It is also used as a refrigerating substance in various
industrial and scientific processes, and new uses are being found for
it from year to year.
Like many other latter-day miracles, compared with which the alleged
feats of necromancy seem tame and puerile, the liquefaction of air is
founded on quite simple principles. The earliest commercial process
was invented, in its main features, by Linde in 1895, and the newer
processes are merely modifications of this one.
Experiments of the English physicists Joule and Thomson showed that
when a gas under pressure is forced through a small orifice, beyond
which it expands, it undergoes a certain amount of cooling. This fall
in temperature, known as the “Joule-Thomson effect,” is generally quite
small, but Linde devised a means of multiplying it in his “regenerative
cooling process.” The air to be liquefied is first compressed to,
say, 100 atmospheres, cooled as much as possible by water, and passed
through a long spiral tube. At the end of the spiral it escapes through
a small nozzle, and is thus somewhat further cooled by the effect above
mentioned. This cooled air then passes back around the spiral tube, and
causes still more cooling of the air in the latter. The escaping air is
again compressed and goes through the same process as before. Thus its
temperature grows constantly lower, until finally the stream issuing
from the nozzle is a liquid instead of a gas. The liquid collects in a
reservoir, from which it can be drawn off when desired.
Public-domain text, read in full here on John Shaqi.
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