Here we find the modern doctrine of _electrons_ or unitary atomic
charges, clearly formulated in 1834. In the course of this speculation
he remarks that “if the electrical power which holds the elements of
a grain of water in combination, or which makes a grain of oxygen or
hydrogen in the right proportions unite into water when they are made
to combine, could be thrown into the condition of _a current_, it
would exactly equal the current required for the separation of that
grain of water into its elements again.” And all this years before
there was any doctrine of the conservation of energy to guide the mind
of the philosopher! The passage just cited contains the germs of the
thermodynamic theory of electromotive forces worked out a dozen years
later by Sir William Thomson (now Lord Kelvin), by which theory we can
predict the electromotive forces of any given chemical combination from
a knowledge of the heat evolved by a given mass of the product in the
act of combining.
[Sidenote: ANOTHER UNSUCCESSFUL QUEST.]
The eighth series of the researches, which was read in June, 1834,
deals chiefly with voltaic cells and batteries of cells. He is now
applying to the operations inside the primary cell the electrochemical
principles learned by the study of electrolysis in secondary cells.
His thoughts have been incessantly playing around the problem of
electrolytic conduction. He was convinced that the forces which shear
the anions from combination with the cations and transfer them in
opposite directions must be inherent before the circuit is completed,
and therefore before any actual transfer or movement takes place. “It
seems to me impossible,” he says, “to resist the idea that it [the
“transfer,” or “what is called the voltaic current”] must be preceded
by a _state of tension_ in the fluid. I have sought carefully for
indications of a state of tension in the electrolytic conductor; and
conceiving that it might produce something like structure, either
before or during its discharge, I endeavoured to make this evident by
polarised light.” He used a solution of sulphate of soda, but without
the slightest trace of optical action in any direction of the ray. He
repeated the experiment, using a solid electrolyte, borate of lead, in
its non-conducting state, but equally without result.
During the time of these electrochemical researches in 1833 and 1834,
Faraday’s activities for the Royal Institution were undiminished. In
1833 he gave seven Friday discourses, three of them on the researches
in hand, one on Wheatstone’s investigation of the velocity of the
electric spark, and one on the practical prevention of dry rot in
timber, which was afterwards republished as a pamphlet, and ran to
two editions. In 1834 he gave four Friday discourses; two on his
electrochemical researches, one on Ericsson’s heat-engine, and the
other on caoutchouc.
Public-domain text, read in full here on John Shaqi.
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