This series of researches was published in January, 1833. In April
of the same year he sent to the Royal Society another paper--the
fourth series--on electric conduction. It arose from the surprising
observation that, though water conducts, ice acts as a complete
non-conductor. This led to an examination of the conducting power of
fusible solids in general. He found that as a rule--excepting on the
one hand the metals, which conduct whether solid or liquid, and on the
other hand fatty bodies, which are always non-conductors--they assume
conducting power when liquefied, and lose it when congealed. Chloride
of lead, of silver, of potassium, and of sodium, and many chlorates,
nitrates, sulphates, and many other salts and fusible substances were
found to follow this rule. All the substances so found to act were
compound bodies, and capable of decomposition by the current. When
conduction ceased, decomposition ceased also. An apparent exception was
found in sulphide of silver, which, when heated, acquired conducting
powers even before it assumed the liquid state, yet decomposed in the
solid state. This led him on to study electro-chemical decompositions
more closely. Here he was following directly in the footsteps of his
master Davy, whose discovery of the decomposition of potash and soda
by the electric current had been one of the most prominent scientific
advances resulting from the invention of the voltaic cell. The fifth
series of researches, published in June, 1833, embodies the work. He
first combats the prevailing opinion that the presence of water is
necessary for electro-chemical decomposition; then analyses the views
of various philosophers--Grotthuss, Davy, De la Rive, and others--who
had discussed the question whether the decompositions are due to
attractions exercised by the two poles of the electric circuit. This he
contests in the most direct manner. Already he has reason to believe
that for a given quantity of electricity passed through the liquid
the amount of electro-chemical action is a constant quantity, and
depends in no way on the distance of the particles of the decomposable
substance from the poles. He regards the elements as progressing in two
streams in opposite directions parallel to the current, while the poles
“are merely the surfaces or doors by which the electricity enters into
or passes out of the substance suffering decomposition.”
Amongst the laboratory notes of this time are many which were never
published in the “Experimental Researches,” or of which only brief
abstracts appeared. Some of these are of great interest.
Here is one literally transcribed:--
26 Feb. 1833.
Public-domain text, read in full here on John Shaqi.
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