Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
The fuel value of the iron and sulphur is augmented at a rate much
greater than their actual increase in numerical proportion would
suggest, on account of the much higher calorific intensity of large
and massive quantities of fuel burned at once than that resulting from
smaller amounts disseminated throughout a mass of inert material such
as gangue.
The practical application of the pyritic principle to blast-furnace
practice thus involves the employment of the furnace as a medium
for conducting the required oxidation of the charge, as a result of
which, the heat of this combustion proportionately reduces the amount
of carbonaceous fuel required for the smelting and separation of
the products, whilst at the same time the desired concentration is
also effected. The basis of such working is, therefore, the powerful
oxidising action within the furnace itself, and the fullest utilisation
of the heat resulting from this oxidation of the sulphides.
In order to supply the heat necessary for the reactions and fusions
of smelting, a definite quantity of fuel is essential in the furnace.
In those cases where the proportions of sulphide are not sufficient
to supply the required amount, a supplementary quantity of coke fuel
becomes requisite.
The extent to which coke is necessary for the smelting operations
decides whether the process may be termed “true pyritic” or “partial
pyritic” smelting. In the former case, the coke allowance may be
reduced to such small proportions that its influence in the smelting
zone of the furnace is practically negligible.
In partial pyritic smelting, coke is necessary to the extent of
supplementing the heat derived from the sulphide fuel, and the
proportion employed in modern work is reduced to the lowest possible
quantity. Not only is economy in coke allowance one of the chief
essentials in furnace management, but the presence of a larger amount
than is absolutely necessary decreases the efficiency of the smelting
operations, since, owing to its reducing action and its consumption of
the oxygen in the air blast which is to be utilised for the combustion
of the iron and sulphur, the concentration of the copper in the
resulting matte would be decreased.
The extent to which the pyritic principle may be operated in actual
working depends in the first instance upon the nature of the charge
itself, especially upon the relative proportions of copper, iron, and
sulphur, and on the quantity of gangue. Since these vary in the ore
supply of different localities, the extent to which the principle may
be applied and the coke consumption be reduced, will be subject to
alteration accordingly.
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