Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
It is well known that within certain broad limits of silica content,
slags will fulfil these conditions to a greater or less extent, whilst
the most suitable and economic slag under any particular circumstances
is decided, as stated above, by the composition of the charge, the
quantity and character of the available fluxes, and the previous
experience with the furnace. The limits of the silica content for
suitable slags as just indicated are fixed by several well-known
general properties of the silicates.
Speaking broadly, and from the point of view of the more or less
ferruginous silicates constituting copper-smelting slags, the
more basic silicates—such as the subsilicate class (oxygen in
acid : oxygen in base < 1 : 1)—are generally characterised by high
formation-temperature, and by being very fluid, thin and fiery, dense
and corrosive. On the other hand, the more acid silicates, such as
those of the multi-silicate class (oxygen in acid : oxygen in base >
2 : 1) are characterised by lower formation-temperature and low density,
and by being thick and viscous.
As the silica content within this range of silicates increases, the
melting point is lowered and the specific gravity is reduced, features
which are very advantageous from the point of view of the production
of clean slags. Their fluidity, however, decreases, and a very high
temperature is thus required in order to render them sufficiently
limpid to run freely from the furnace. On this account the highest
proportions of silica usually considered feasible in a slag, correspond
to the bisilicates of the representative composition, MO. SiO_{2}.
With high temperature conditions in the furnace and rapid working,
such slags can be dealt with successfully, and if the charges are
necessarily highly siliceous, it may be advantageous from the economic
point of view to work with this class of slag.
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