Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
The presence of lime silicate with the iron silicates has a marked
influence on the fluidity of the slags, even when they are more highly
siliceous, whilst on account of the lower atomic weight of calcium,
lime will, weight for weight, flux off a greater quantity of silica
than will ferrous oxide. In forming a slag of similar oxygen ratio,
thus—
Mono-silicate of lime, 2CaO . SiO_{2},
Lime : silica :: 112 to 60, or 1 part to 0·54 part.
Mono-silicate of iron, 2FeO . SiO_{2},
Iron oxide : silica :: 144 to 60, or 1 part to 0·42 part;
hence for the production of a slag of the same oxygen ratio, less
weight of lime would be required to flux off the same weight of silica;
in other words, the replacing values of the two oxides are as 112 to
144, or 7 to 9.
Of the other bases which are occasionally present in slags, the
proportions of the oxides of magnesium and zinc are sometimes
considerable, the calculations being analogous to the previous
cases. The case of alumina is anomalous, and its behaviour in slag
production is not definitely understood. Many experienced workers
hold the view that it tends to act either as acid or base, according
to the proportions of silica. Thus, in a very siliceous slag, alumina
in moderate quantity behaves as a basic oxide, forming aluminium
silicates, and in very basic or low silica slags the alumina appears
either to neutralise some of the excess base, acting as an acidic
oxide, or to dissolve as such in the slag, whilst in intermediate cases
it possibly behaves partly as an acid and partly as base. This view
has recently been questioned, and it has been suggested by Shelby that
alumina always acts as an acid in the formation of slags. The matter is
thus one which requires further considerable investigation.
Usually neither alumina nor zinc oxide behave very satisfactorily in
the furnace when present in large quantities, tending to thicken the
slags and to promote viscosity.
=Anaconda Practice in Charge Calculations.=—An example of some of the
practical considerations which enter into the calculation and making up
of charges is well illustrated in certain particulars of the practice
as conducted at Anaconda. Details of the materials charged over a
period of one month are indicated in Table X. The important charge
constituents available in large quantity include:—
Cu. SiO_{2}. Fe(O). S.
% % % %
First-class smelting ore, 8·6 54·0 13·6 14·0
Concentrates, 10·9 26·0 32·0 32·0
Briquettes, 5·0 50·0 13·0 13·0
Lime-rock (flux), .. .. .. ..
Old converter slags and residues, .. .. .. ..
TABLE X.—BLAST-FURNACE CHARGE CALCULATIONS—TOTAL CHARGE, ALL FURNACES.
Public-domain text, read in full here on John Shaqi.
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