Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
At the Mount Lyell Smelter, where Sticht operated, the charge extends
about 12 feet above the tuyeres. In the upper 6 or 7 feet, elemental
sulphur is driven off from the pyritic materials by the effects of heat
alone, and the furnace gases in this zone consist chiefly of nitrogen,
SO_{2} (from the bessemerising), sulphur vapour, a little CO_{2}, but
practically no free oxygen. About half-way down, the temperature is
sufficiently high to melt out the fusible sulphides from the charge;
these liquate and trickle unchanged through the still solid masses of
gangue and silica-flux, until they meet with free oxygen of the air
blast, when they are oxidised and burnt up with great rapidity and with
the evolution of intense heat. This bessemerising zone extends from
a short distance above the tuyeres to a point where all the oxygen
is used up by the iron and sulphur. The distance is variable, but is
probably some 2 feet or so. At this level the ferrous oxide produced
is instantaneously seized by the white-hot particles of free silica
with the production of _a silicate slag, the composition of which
corresponds to the silicate whose formation temperature is equal to
that prevailing in this bessemerising zone_.
_Control of the Operations._—It has thus been established that the
oxygen of the air blast entering the furnace through the tuyeres
is practically all expended in this bessemerising of the liquated
sulphides in the narrow bessemerising zone, and that it does not
operate at all by any roasting reactions in the upper part of the
furnace, as had been formerly supposed.
From this knowledge it therefore becomes possible to indicate the
essential factors which control the successful operation of true
pyritic smelting. The degree of bessemerising depends upon the amount
of air supplied for the oxidation of the sulphides, and upon the
quantity of siliceous flux present to slag off the iron oxide produced.
The actual smelting takes place at the focus where the liquated
sulphides are instantaneously bessemerised, and the more rapid this
oxidation, the more intense are the reactions and the higher the
temperatures which result.
For successful pyritic smelting it is, therefore, essential that there
shall be present—
(_a_) Sufficient sulphides in the charge to give out
the heat necessary for the smelting and for the
thorough fusion of the products.
(_b_) Sufficient oxygen (air) for the rapid and
necessary oxidation of this sulphur and iron.
(_c_) Sufficient free siliceous flux for the satisfactory
slagging of the iron oxides produced.
Public-domain text, read in full here on John Shaqi.
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