Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
It is very often possible by such careful attention to gradually bring
a furnace back to smooth running. It occasionally happens, however,
that the conditions gradually become worse, and the furnace commences
to show signs of “gobbing.” This is indicated at the top of the charge
by the formation of crusts round the side and end walls, whilst from
the slag spout below, there issues a much reduced quantity of thick
siliceous slag, together with an abundant stream of thin low-grade
matte. The furnace gradually ceases running, and it becomes necessary
to stop its working, to take down the furnace jackets, bar out the
debris, and restart operations. This is usually not so objectionable
a procedure as it might appear, and indeed, within certain definite
limits, such a course may economically be sound policy. In the modern
operation of pyritic practice it often pays better to risk the
occasional gobbing up of a furnace and clear out the debris, than to
work with so large a quantity of coke as would avoid such a necessity.
Not only is the modern furnace so designed and constructed as to entail
but comparatively little trouble in cleaning out in this manner, but
such practice, even if temporarily a necessary evil, may, in places
where coke is expensive, and where conditions for pyritic smelting are
otherwise favourable, be, within certain definite limits, actually the
most profitable. It is by the taking of these risks, combined with
further experiment and working experience in manipulation, such as in
charging methods, blast conditions, and the height and distribution
of charges, etc., that the ultimate continuous and successful working
at still lower costs may be attained and the true pyritic process be
worked as continuously as ordinary smelting practice. Short campaigns
are not, therefore, unusual under the present conditions of true
pyritic smelting, and the cleaning out of the generally fairly loose
debris is accomplished with moderate ease, from 24 to 36 hours being
the usual time required to take down, clean out, and restart a furnace,
whilst the cost of such an operation (chiefly in labour) is not, under
the circumstances, excessive. At Tennessee, hard driving and short
campaigns result in lower costs and greater tonnage.
(2) The composition of the slag often prevents high concentration.
It has been indicated that the thermal conditions in the bessemerising
zone of the pyritic furnace tend to the production of highly basic
slags, which, though hot and limpid, are characterised by high density.
Such slags are not conducive to good settling and separation of mattes,
and they tend to occasion high copper losses, because—
(_a_) The difference in density of slag and matte is
not sufficiently great.
(_b_) The solubility of sulphides in the slag increases
with its basicity.
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