Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
It is found that in true pyritic smelting the coke does not reach the
bessemerising zone at all, but that it is completely consumed in the
regions above this point. It is, moreover, not burned by the oxygen of
the air, none of which exists above the tuyere zone, since all this
oxygen is consumed by the combustion of the sulphide. It appears that
the coke is oxidised by the SO_{2} which results from this sulphide
combustion. The examination and analysis of samples of the gases
withdrawn from different parts of the furnace have confirmed this view,
and have elucidated the probable reason for the apparent necessity of
a certain small proportion of coke in the process, under the present
conditions of working. The heat generated from the oxidation of the
coke by the SO_{2} is of much value in preheating the materials of
the charge for the removal of excess sulphur and the liquation of the
sulphides. The amount of heat which is available for this operation
is small, being practically all derived from that carried upwards by
the hot gases leaving the smelting zone, and none is obtainable by the
usual processes of coke or sulphide oxidation in the upper regions of
the furnace, since no available oxygen is believed to get past the
bessemerising zone and reach these upper areas. It is indeed necessary
for the success of pyritic smelting that such oxidation or roasting
of sulphides in the upper part of the furnace should be prevented,
since every available particle of iron sulphide is required for heat
production at the smelting zone, by its combustion there, and any
oxidation elsewhere not only deprives this zone of fuel, but spreads
the heat over too wide an area for sufficiently intense combustion.
Thus, by supplying an additional amount of heat to the upper parts of
the furnace, where heat is needed to assist in the preparation and
liquation of the sulphides, the extra coke, in being oxidised by the
SO_{2} without robbing the tuyere zone of fuel or air, just fulfils
its useful purpose at the required place, in such a way as to keep the
smelting operation running smoothly.
The presence of more coke than is absolutely necessary for the
fulfilment of this purpose is, in addition to its extra cost, of
no advantage, and in true pyritic smelting none should reach the
tuyere zone, since it introduces a reducing influence where the most
marked oxidising effect is required. By consuming oxygen for its
combustion, it deprives the iron sulphide of this material, less iron
is, therefore, oxidised, and the matte is consequently increased in
quantity and lowered in grade, whilst the amount of iron carried into
the slag is decreased.
Public-domain text, read in full here on John Shaqi.
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