Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
1·25 per cent. of coke is about the minimum quantity with which it is
found practicable to maintain satisfactory working of the furnace under
present conditions, 0·5 per cent. has been worked with occasionally,
and none at all over certain short periods of time. The average
quantity employed is from 2 to 3 per cent., and when about 5 per cent.
is used, coke reaches the tuyere zone and the process ceases to be
truly pyritic—the reactions and smelting conditions become entirely
changed.
It does not seem unlikely that, as knowledge of these conditions
increases and as the mechanism of the process becomes more generally
understood, modifications in furnace design and blast conditions may
lead to the successful operating of the pyritic process entirely
independent of the use of coke fuel.
_Heating of the Blast._—For true pyritic smelting it has been shown
in practice that the use of heated blast possesses no advantages;
many smelters operating the process have tested the effects, and have
usually given the method up, whilst the work of Sticht and Peters
affords valuable evidence and close argument as to the reasons for
its unsuitability. Success in true pyritic working depends upon the
intensity of oxidation of the sulphides, and upon the localisation
of the resulting heat at the narrow bessemerising zone situated just
above the tuyeres. The greater the quantity of iron which is there
oxidised per minute, the better is the concentration, the greater is
the smelting and fluxing intensity and the higher is the resulting
temperature. Since the character and composition of the slag vary
in accordance with these conditions, depending largely upon the
temperature in the tuyere zone, the furnace works most rapidly and
satisfactorily when slags of high formation temperature are being
produced. These can only be formed if much iron is being oxidised,
because iron is the chief fuel in the process. The addition of extra
heat by warming the blast appears to allow of the formation of silicate
slags possessing a lower formation temperature, such slags are less
basic, and consequently less iron need be oxidised and slagged off per
minute in order to produce them. Less iron sulphide fuel is, therefore,
burned, and the reaction intensity at the tuyere zone is reduced, so
that the necessary heat margin for satisfactory smelting may not be
attained. The extra heat carried in by the warmed blast may not be
sufficient to compensate for that which is lost owing to this decrease
in oxidation intensity; the furnace consequently tends to work cold,
whilst the excess air supply leads to the production of over-fire, by
the oxidising of sulphides higher up in the charge.
Public-domain text, read in full here on John Shaqi.
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