Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
=Development of the Process for Bessemerising Copper Mattes.=—The
success of Bessemer’s process, which was applied in 1856 to the
production of steel by blowing air through molten cast-iron, led to a
suggestion for its application to copper mattes and to some experiments
on the subject by Semenikow, a Russian engineer, ten years later. It
was not until 1878 that any further work was conducted on a practical
scale. In that year John Holway suggested and worked out the scheme
already referred to, the principles of which as outlined by him, form
the foundation of the pyritic and converter practice of the present
time. Air was blown through heated Rio Tinto pyrites in an ordinary
Bessemer steel converter and the experiments met with considerable
success. The apparatus was, however, not deemed convenient, as the
process worked very intermittently and large quantities of slag were
produced which required to be poured off at intervals, whilst the
position of the tuyeres in this form of converter was found to be
unsatisfactory. There are many practical difficulties in employing the
same kind of apparatus for the converting of copper mattes as for the
bessemerising of cast-iron into steel. In the first instance, the final
steel product differs but little in weight or bulk from the original
charge, whilst the process produces but little slag, owing to the
comparatively small proportions of silicon and manganese which require
to be oxidised—whereas in copper converting, the quantity of slag
produced is almost equal in weight to the amount of matte originally
charged, whilst the resulting copper product amounts to less than
one-half of this weight. Further, in bessemerising cast-iron, the blow
is of very short duration; in copper matte converting, it occupies
more than two hours, and the relative heat losses are, in consequence,
markedly different. Finally, the lining of the steel converter chiefly
serves to protect the shell; its function in the copper converter was
to act also as flux for the iron oxides produced on blowing.
In Holway’s final form of apparatus for the pyritic smelting of copper
ore to metal, the introduction of siliceous material as a flux for the
iron oxide and the use of basic lining were arranged for, with the
object of overcoming the difficulties caused by the corrosion of the
siliceous lining which acted as flux.
Public-domain text, read in full here on John Shaqi.
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