Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
Keller’s report on basic linings in 1890 stated that they could not
be employed successfully, because (_a_) basic material, being a good
conductor, caused the outside of the converter to become too hot and
the inside too cold; (_b_) such material broke up easily and so was
unsuitable for use in permanent linings; and (_c_) even when basic
linings were employed, the silica which was added as flux, refused
to combine with the iron oxides. These views were very generally
accepted for some years, until Baggaley’s persistent efforts and
finally those of Pierce and Smith showed that by perfecting the
constructional methods and details, by preventing heat losses as much
as possible, and by operating on very large masses of hot material,
the above difficulties could all be overcome and the basic lining
successfully employed. The lining is of magnesia brick, and is 9 inches
in thickness, except at the tuyeres, where the bricks are 18 inches
thick. In the bottom of the converter and extending to within 18 inches
of the tuyere level is placed a filling of ordinary firebrick, which
is 13½ inches thick in the middle and 4 inches thick at the sides. The
magnesite bricks are laid in dry magnesite powder, except near the
tuyeres, where a mixture of magnesia and linseed oil is used. Expansion
cushions of wood are inserted at intervals along the side of the fresh
linings which are then “seasoned” with molten copper.
The required quantity of siliceous flux, as calculated, is now
successfully introduced by dumping it into the converter, and pouring
the matte charge upon it.
=The Grade of Matte for Converting.=—The grade of matte which is
economically the most profitable to treat in the converter is a factor
of great importance, since, if limits be fixed, the preliminary
smelting stages for matte production are made less flexible, whilst in
order to obtain matte of the correct grade, the smelting operations may
require to be conducted at greater cost, or else additional smeltings
for further concentration of the first matte may be necessitated—as is
the case, for instance, in pyritic smelting at present.
The grade of a matte is usually expressed in percentages of copper,
but from the standpoint of the practical converter operations, the
proportion of iron is the factor which decides the suitability or
otherwise of the matte for treatment, and since mattes may be regarded
as mixed sulphides of iron and copper, a matte rich in copper is
correspondingly low in iron contents, whilst a low-grade matte is high
in iron.
Public-domain text, read in full here on John Shaqi.
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