Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
Owing to the frequent relining of these converters being then no longer
necessary, mechanical difficulties of conveying the converter bodies
to the relining shops are lessened, and larger converter units can
now be employed, treating, even at the present stage of development,
between six and seven times as large an amount of matte as formerly.
By operating on such big charges, pouring off slag as produced, and
adding fresh matte and flux without fear of destroying the lining, the
difficulties attending the converting of low grade mattes have been
successfully overcome.
The limit to the grade of matte economically suitable for the process
will depend, in the future, chiefly upon the comparative costs of
effecting the required concentration up to any desired grade, in the
blast-or reverberatory-furnace, or in the converter.
The modern smelting scheme appears, therefore, likely to develop into
the preliminary smelting of the ores by the cheapest method available,
for matte of a grade best suited economically to the running of the
furnace, the grade being independent of any rigid limit for the
subsequent converting operations—the matte being then bessemerised as
usual.
=The Converting Process=—_Acid Lining_.—There are two main stages in
the converting of copper mattes. The first is essentially elimination
of iron sulphide; the second, elimination of the remaining sulphur.
The product of the first main stage is a white metal, practically pure
copper sulphide, the iron of the matte having been slagged off in the
form of silicate, and the corresponding sulphur eliminated as SO_{2}.
The reactions during this stage are well known: the oxygen of the air
blown in, yields oxides of iron and of sulphur, as well as some copper
oxide. The latter, immediately reacting with iron sulphide which still
remains, re-forms copper sulphide, with the production of more iron
oxide. The iron oxides are fluxed by the siliceous materials present,
forming ferrous silicate slags. The iron oxidation is productive of the
greater part of the heat in the operation, and high temperature usually
marks this stage of the process, which may be termed “the slagging
stage.”
The flame which issues from the converter during this period is usually
characterised by a green colour, caused apparently by the formation of
iron-silicate slag.
When this stage is completed and the slag poured off, the white metal
is blown up to blister copper—this constituting the second main stage
of the process. The chief reactions are those of sulphur elimination
and the production of metallic copper, caused by the action of some of
the copper oxide first produced, upon the copper sulphide still present.
The flame during this period is small, thin, and fairly non-luminous,
usually of a red-purple to bronze purple colour.[16]
Public-domain text, read in full here on John Shaqi.
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