Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
_Working of a Typical Charge in Silica-lined Converter._—The Anaconda
converter plant is now being operated with basic linings. The former
practice at this works was representative of the best type of
acid-lined working, and the following description, based upon this
practice, is typical of the method in general use. There were in
operation twelve converter stands of the dimensions previously given.
Normal working was to convert the 45 per cent. copper matte to white
metal, to pour off slag, blow to blister copper, and pour the resulting
metal—in regular sequence.
The colour-changes in the flame during bessemerising are indicated in
the colour-photographs reproduced in the frontispiece.
[Illustration: Fig. 66.—Composition of a Charge during Bessemerising
Operation.]
[Illustration: Fig. 67.—Pouring Slag, Anaconda.]
Seven to 8 tons of matte at an average temperature of 900° C. are
charged into the converter, which is in an upright position with the
blast on (16 lbs. per square inch). The operation of charging occupies
three minutes. A few lumps of coal are thrown in, a vigorous action
commences, copious and heavy white fumes and smoke and a full red to
red-brown flame being emitted. The converter is now turned slowly back,
so as to bring the tuyeres more completely under the charge and ensure
more rapid and efficient oxidation, and the blow proper then commences.
The flame drops for a time, continuing to be of a red to red-purple
colour for two to eight minutes, after which, green commences to show
in the red smoky flame (A), indicating that the first or slag-forming
period of the blow is beginning. The green colour becomes more
prominent and continues for 40 to 45 minutes (B). A preliminary pouring
off of slag is then usually made, owing partly to the danger of violent
or even explosive interaction which might otherwise occur between
matte and slag, and also with the object of keeping down the copper
losses in the slag by removing the greater portion of the latter at as
early a stage as possible. The blowing is then continued. Flashes of
blue now occasionally appear in the flame, and gradually increase in
number until the flame becomes blue-white (C), which indicates that
most of the iron has been slagged off and that the white metal stage
is reached. The blue-white colour of the flame is to be attributed
to the production of copper silicate, owing to the tendency of the
copper oxide formed by the air blast at this stage, to flux off, and
to produce the silicate rather than attack the copper sulphide. This
formation of copper-silicate is particularly liable to occur in the
presence of much slag and at high temperatures, factors which are well
known to encourage this selective combination, and which prevail at
this stage.
The blowing up to white metal takes about one hour.
Public-domain text, read in full here on John Shaqi.
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