Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
Slag is then poured off again, until an iron rabble held under the
stream commences to show signs of “metal” which give an appearance
of spots of grease on the blade. The charge is then usually “doped.”
“Dope” consists of highly cupriferous scrap, cleanings, slags,
residues, also some siliceous material, added partly for the purpose of
cooling down the charge which tends to become overheated at this stage.
The converter is turned up again and the blowing is resumed in order to
convert the white metal to blister copper.
The main reaction which now proceeds is represented by the equation
Cu_{2}S + 2Cu_{2}O ➡ 6Cu + SO_{2}.
This stage of the blow also occupies about one hour or more, according
to circumstances. It commences with a vivid red flame accompanied by
smoke, but this soon dies out and a thin purple, almost colourless,
flame results, which continues practically unchanged for the remainder
of the blow (D). The temperature of the white metal is to some extent
judged by the appearance of the flame, a red-brown colour indicating
the correct temperature. If the colour be too red, the metal is too
cool, and coal is thrown in; if the tint be too orange, the temperature
is too high, and dope is added. Constant punching of the tuyeres by
long steel chisels is required during this stage of the blow, owing
to the lessened heat production due to diminution of iron, and also
to the marked tendency for the liberated copper to chill round the
tuyeres. The end of the blow is most difficult to judge, and although
the size and colour of the flame offer some criterion, the usual and
most important guide is the emission of small shots of copper which no
longer stick to the hood situated above the converter throat, but which
rebound from it. This is the stage where the skill and judgment of the
skimmer are most tried.
When the blow is considered satisfactory, the character of the metal is
further tested by pouring a small quantity on to the floor—a rugged and
uneven surface indicating satisfactory metal. If poured too soon, the
copper is coarse and impure; if poured too late, heavy losses in the
slag result, owing to excessive oxidation of the metal.
The copper is then poured into a ladle, and conveyed to the refining
and casting furnaces.
The whole operation for a straight run occupies about two hours, but
the time required in general naturally depends upon the rapidity of
working, and particularly on the grade of matte, and the volume and
pressure of the blast.
Public-domain text, read in full here on John Shaqi.
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