Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
The further treatment of the converter metal depends to a large extent
upon its composition, and the purpose for which it is intended. The
matte-smelting operations on copper ores bring about the elimination
of the greater part of the constituents accompanying the copper. The
converter-grade matte may, however, in addition to the copper, iron
and sulphur, also contain considerable proportions of easily reducible
impurities of the ore, possessing a greater tendency to enter the matte
than to be oxidised and eliminated in the slag. Such constituents may
include gold and silver (practically all concentrated and retained in
the cupriferous product), arsenic, antimony, bismuth, selenium and
tellurium (retained to very considerable extent), as well as lead,
zinc, nickel and cobalt (in much smaller proportions). The amount of
these latter impurities ultimately retained in the converter matte
depends very largely upon the proportions originally present in the
ore, and upon the smelting conditions.
Under the strongly oxidising conditions of the Bessemer process the
copper retains but small quantities of impurity, and those which do
remain in ordinary converter metal may be broadly divided into two
classes[17]—(_a_) those which are oxidisable with comparative ease, and
(_b_) those which persist in the metal even under oxidising influences,
unless treated by special means. The former include iron, sulphur, and
zinc; the latter, arsenic, antimony, bismuth, selenium, tellurium,
gold, and silver. Keller gives the following figures for the average
elimination of the impurities in the converter:—
Iron, 99 per cent.
Sulphur, 99 "
Zinc, 99 "
Cobalt, 99 "
Bismuth, 97 "
Lead, 96 "
Arsenic, 81 "
Antimony, 71 "
Selenium, 47 "
Tellurium, 40 "
Nickel, 37 "
Of the persistent elements, the retaining of the gold and silver in
the converter-copper is a factor of much economic advantage, but the
other impurities are curiously just those which are characterised by
possessing most injurious effects on copper intended for electrical
work—for which purpose most of the material is employed.
The demand for particularly pure metal in electrical and conductivity
work therefore usually necessitates a further purification of the
converter-copper (unless it be an exceptionally pure brand) and the
production of metal specially free from the injurious constituents
which persist to a small but sometimes very appreciable extent in the
metal under the ordinary oxidising conditions. The presence of silver
and gold in the copper may afford in many instances sufficiently good
reason for a separating process independently of the market for the
pure copper itself.
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