Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
oxygen (equivalent to about 6 per cent. of Cu_{2}O) must be introduced.
In the refining practice as conducted by the Welsh process, much of
this aëration took place during the slow melting down of the crude
blister copper, and subsequently during the flapping operations with
the rabble; but the use of the air-blast hastens this oxidation
considerably, especially as the metal is now often directly poured
into the furnace in a molten condition, so that oxidation during
melting is not possible. It is essential to defer this final oxidation
and elimination until it can be conducted at the refining furnaces
rather than to attempt it in the converter, since the refining furnace
allows of the operation being performed much more gradually and under
better control, whereas if conducted in the converter, the necessarily
vigorous action would occasion unduly heavy losses of copper in the
slag and probably excessive oxidation of the metal.
During the aëration, the furnace contents are continually added to, by
additional ladles-full of metal, and usually by the time the furnace
is filled the air-blast has oxidised most of the impurities from the
metal. These have entered the slag, and the copper has become “dry,”
owing to the necessary super-aëration. If this stage has not been
reached, the sample often shows “sprouting” (also known as “spewing”
or “throwing a worm”), which is caused by the escape of SO_{2}, and
indicates that all the sulphur has not been eliminated. In that case
the blowing is continued until small samples ladled out from the bath
exhibit the characteristics of dry copper, viz.: the depression down
the middle line of the ingot, brittleness of the metal, and a purplish
brick-like fracture.
These preliminary operations may occupy some three or four hours or
more.
(_b_) _Poling and Bringing to Pitch._—The oxidation having proceeded to
the required stage, the highly cupriferous slag is skimmed off, after
being first thickened with ashes from the fire-grate, and the poling of
the metal is then commenced. This operation is conducted by immersing
poles of timber, three to six at a time, in the metal, holding them
well under the surface and pushing them further in as the ends burn
away. It is essential that the timber should be green and not dry, and
preferably it should be hard wood, such as birch, beech, or oak. The
poles are usually as long as possible, and are from 6 to 8 inches
thick at the butt end. The function of the wood, particularly during
the early stages is, to a great extent, mechanical, and any chemical
changes effected are by indirect action.
The poling operation really consists of two stages, the first of which
is the final elimination of SO_{2} retained by the metal, and the last,
the actual reduction of the excess oxide and the “bringing of the metal
to pitch.”
Public-domain text, read in full here on John Shaqi.
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