Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
The green timber, when inserted into the copper, liberates large
amounts of moisture and reducing gases which agitate the bath
considerably and “shake” the gas out of the metal more or less
mechanically, replacing, at the same time, some SO_{2} by CO and
hydrocarbons which copper possesses the power of absorbing. When the
SO_{2} has been satisfactorily eliminated, the reduction stage is
arrived at, and this is conducted in a manner similar to the familiar
poling operation of the Welsh process. The surface of the bath is
completely covered over with a layer of coke, anthracite, or charcoal,
and more poles are inserted. The exact mechanism of the operation has
not yet been definitely traced, but the action of the wood at this
stage is partly of a mechanical and partly of a chemical nature. The
reducing gases liberated by the charring and destructive distillation
of the wood have themselves a reducing action on the oxides which are
dissolved in the dry copper, but an important feature of the action of
these gases is the agitation and splashing which they occasion, thus
bringing the molten metal into close and vigorous contact with the
layer of reducing carbonaceous material maintained upon the surface of
the bath.
Poles are inserted usually two or three at a time, and samples are
constantly taken and examined for surface indications and for fracture.
This preliminary refining operation usually has for its chief object
the preparation of a fairly pure metal which will yield a sound, clean,
and even anode casting, and which is not required at this stage to pass
the rigid mechanical tests essential for the market product. In this
case it is therefore usual to carry the poling operation only to such a
degree that the samples ladled out and cast into small ingots solidify
with the even, smooth surface desired and which is characteristic of
“tough-pitch copper”—irrespective of any special mechanical properties
of the metal. If the test is satisfactory, the metal is ready for
casting.
The poling occupies some hours, and usually from 40 to 50 poles of wood
are used up before the metal is in a suitable condition for casting.
During these operations the coal fire in the grate is manipulated in a
manner best suited to the various stages of the process; there may thus
be an oxidising flame during the early part of the refining, but the
flame must be of a reducing character whilst poling is in progress.
Public-domain text, read in full here on John Shaqi.
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