Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
(_d_) Special tanks are required, as the protecting lead liner
cannot be employed, since the danger of current-leakage through it
is increased, owing to the higher voltages required. Hence special
acid-resisting material, such as slate, is necessary, the expense of
which is considerable.
(_e_) The cost of stripping the cathodes is high, and the operation is
often difficult.
(_f_) The cost of maintaining the plant is greater.
The special advantages of the multiple system are that—
(1) It is applicable to all grades of metal;
(2) It permits of either high or low current-density
being employed;
(3) It permits the use of cheaper lead-lined wooden
tanks for working;
(4) Anode plates may be used without previous refining,
if so desired.
It is, however, general to carry out this preliminary refining, which
yields sounder anodes, keeps the electrolyte purer, and promotes the
more regular working of the electrodes and electrolyte—although some
smelters still cast the anodes direct from converter metal.
Summarising, it is found generally that—
(1) A marked saving is effected in operating the
multiple system (this has been estimated by Barnett,
at as much as $2 per ton of refined metal—8s. 4d.);
(2) A greater efficiency is obtained, the tank
efficiency of the multiple system being 95 per
cent. compared with 90 per cent. for the series-system;
(3) Less copper is held up in the multiple system,
since less anode copper is required, under like
conditions as regards cathode surface and current
density.
OUTLINE OF THE PROCESS.—The electro-refining industry is a highly
specialised one, and the methods of putting the comparatively simple
underlying principles into practical operation have assumed great
complexity and diversity in detail, concerning which Ulke has collected
and published much valuable information.
The following details have more particular reference to the
multiple system of working, as being the most representative of the
electro-refining methods in general use.
The outlines of the process constitute the passing of direct electric
current through tanks containing acidified solutions of copper
sulphate, employing plates of crude copper as anodes, and depositing
pure metal upon cathode-plates of specially-refined thin sheets of pure
copper. The precious metals and most of the impurities of the anode
metal are liberated as small insoluble particles which gradually settle
to the bottom of the tanks in the form of mud, soluble constituents,
such as iron and zinc, first passing into solution.
_General Conditions—Anodes._—The usual dimensions of the anode-plates
are 3 feet high by 2 feet 6 inches wide and about 2 inches thick; they
are generally cast with lugs, so as to allow of suspension in the
tanks. The anode metal is usually brought by a preparatory operation,
to as high a state of purity as is economically practicable—
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