Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
A large number of tanks are employed at the refineries, and they are
usually arranged in series, the anode plates of one vat being connected
to the cathode plates of the neighbouring one, the current thus passing
from one vat to the other through the entire system.
Various other methods of arranging the electrodes have been favoured
from time to time, and of these the _series-system_ is the most
important, this being still in use at several large refineries, though
it has been generally superseded by the multiple method.
The plan underlying the series method was that of avoiding the
trouble and expense of preparing and working with the special cathode
sheets of pure copper as are necessitated by the multiple system.
In the series-method, each anode was made to serve as a depositing
surface for the pure cathode copper produced by the operation, so
that as impure anode copper was dissolved away on one side of the
“anode”-plate, pure copper was gradually deposited upon the other side.
This system appeared, therefore, to have several marked advantages to
recommend it, but in practical operation many difficulties in working
and several serious disadvantages were encountered. The chief points in
favour of the series-system are—
(_a_) Smaller first cost of the installation, particularly in the
matter of electrical connections, since the multiple system requires
heavy leads running along each side of the tank, as well as close
attention to the providing of good contacts, in order to connect all
the anodes and all the cathodes together with a minimum of current
leakage. In the series-method, the plates are readily connected one to
the other.
(_b_) The great saving of the cost of preparation and arranging for
specially pure cathode plates, this constituting a very important
factor in the costs of the multiple process.
(_c_) The output of metal per vat is greater.
On the other hand, the disadvantages of the system, except under
special conditions, are very serious.
(_a_) More scrap is produced and requires re-treating, owing to the
difficulty of separating the new deposit from the remaining portions of
old anode, which often adhere very firmly.
(_b_) Higher voltage through the tanks is required, owing to the
large number of electrodes in series in the bath. Hence the danger of
current-leakage and short circuiting is greatly increased, especially
when impure anodes are used, since they tend to produce conducting
layers of mud on the bottom of the vat.
(_c_) The anode plates have to be made particularly smooth and even on
the surface, since in order to lessen the voltage required, the plates
are brought as close together as possible, in consequence of which,
any excrescences upon the surface greatly increase the danger of short
circuiting. Preliminary furnace-refining and special straightening of
the anodes are therefore essential in connection with the series method.
Public-domain text, read in full here on John Shaqi.
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