Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.Levy, Donald M.
Science
Modern Copper Smelting: being lectures delivered at Birmingham University, greatly extended and adapted and with and introduction on the history, uses and properties of copper.
Levy, Donald M.
Copper -- Metallurgy
The actual refining operation and the furnace employed for the process
are exactly similar to those used in preparing the metal to ensure the
casting of sound ingots, as already described. The operations consist
of a preliminary aëration, by means of which any oxidisable impurity
still remaining in the metal is oxidised out, mainly through the action
of copper oxide which is formed during the process in some considerable
excess.
After the copper has become “dry” or over-oxidised, which condition
is characterised by brittleness, depressed surface, and brick-like
purple-red fracture of the metal, it is reduced by poling and timbering
operations to a definite point, viz.: until a sample ingot of the
metal indicates a maximum of toughness, accompanied by level surface
and bright salmon-coloured silky fracture—it is then of “tough-pitch”
quality.
_The furnace_ employed for the refining has already been described.
One of the main features in which it differs from the ordinary modern
reverberatory smelting-furnace is that owing to the exceedingly high
heat-conducting power of metallic copper, and to the absence of an
insulating layer of non-conducting slag, there is little danger of
much chilling action occurring on the hearth of the furnace; the
temperature may, indeed, often become too high rather than too low.
In consequence, it is not so usual to construct the furnace with a
very massive hearth foundation as for smelting, but to build it upon
a vault or upon a series of piers. With this type of foundation, the
very considerable, but practically unavoidable, absorption of metal
in the hearth-material is reduced to a minimum. It is usual to work
a charge consisting of scrap and oxide in the furnace before the
regular smelting campaign begins in order to “season” the hearth.
This procedure allows the primary absorption of copper by the
hearth-material, and assists its consolidation, whilst the action of
the oxide promotes a surface glazing which lessens the tendency for
further absorption of copper, and gives a good surface to the working
bed. As has been already stated, the hearth is generally built of
brickwork rather than of sand. The furnace is constructed to hold from
80 up to 200 tons of metal. The method of working differs mainly from
that previously described, in that instead of pouring molten copper
into the furnace, as is usual with converter-metal, the cathode plates
must be charged in a different manner.
Public-domain text, read in full here on John Shaqi.
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