The formation I call Porphyritic Conglomerates is the most important and most developed one in Chili: from a great number of sections I find it a true coarse conglomerate or breccia, which by every step in a slow gradation passes into a fine claystone-porphyry; the pebbles and cement becoming porphyritic till at last all is blended in one compact rock. The porphyries are excessively abundant in this chain. I feel sure at least 4/5ths of them have been thus produced from sedimentary beds in situ. There are porphyries which have been injected from below amongst strata, and others ejected, which have flowed in streams; it is remarkable, and I could show specimens of this rock produced in these three methods, which cannot be distinguished. It is a great mistake considering the Cordilleras here as composed of rocks which have flowed in streams. In this range I nowhere saw a fragment, which I believe to have thus originated, although the road passes at no great distance from the active volcanoes. The porphyries, conglomerate, sandstone and quartzose sandstone and limestones alternate and pass into each other many times, overlying (where not broken through by the granite) clay-slate. In the upper parts, the sandstone begins to alternate with gypsum, till at last we have this substance of a stupendous thickness. I really think the formation is in some places (it varies much) nearly 2,000 feet thick, it occurs often with a green (epidote?) siliceous sandstone and snow-white marble; it resembles that found in the Alps in containing large concretions of a crystalline marble of a blackish grey colour. The upper beds which form some of the higher pinnacles consist of layers of snow-white gypsum and red compact sandstone, from the thickness of paper to a few feet, alternating in an endless round. The rock has a most curiously painted appearance. At the pass of the Peuquenes in this formation, where however a black rock like clay-slate, without many laminae, occurring with a pale limestone, has replaced the red sandstone, I found abundant impressions of shells. The elevation must be between 12 and 13,000 feet. A shell which I believe is the Gryphaea is the most abundant--an Ostrea, Turratella, Ammonites, small bivalves, Terebratulae (?). Perhaps some good conchologist (6/1. Some of these genera are mentioned by Darwin ("Geol. Obs." page 181) as having been named for him by M. D'Orbigny.) will be able to give a guess, to what grand division of the formations of Europe these organic remains bear most resemblance. They are exceedingly imperfect and few. It was late in the season and the situation particularly dangerous for snow-storms. I did not dare to delay, otherwise a grand harvest might have been reaped. So much for the western line; in the Portillo pass, proceeding eastward, we meet an immense mass of conglomerate, dipping to the west 45 deg, which rest on micaceous sandstone, etc., etc., upheaved