Nitro-Explosives: A Practical TreatiseSanford, P. Gerald (Percy Gerald)
Science
Nitro-Explosives: A Practical Treatise
Sanford, P. Gerald (Percy Gerald)
Celluloid; Explosives
~Ballistite.~--Nobel's powder, known as ballistite, originally consisted
of a camphorated blasting gelatine, and was made of 10 parts of camphor in
100 parts of nitro-glycerine, to which 200 parts of benzol were then
added, and 50 parts of nitro-cotton (soluble) were then steeped in this
mixture, which was then heated to evaporate off the benzol, and the
resulting compound afterwards passed between steam-heated rollers, and
formed into sheets, which were then finally cut up into small squares or
other shapes as convenient. The camphor contained in this substance was,
however, found to be a disadvantage, and its use discontinued. The
composition is now 50 per cent. of soluble nitro-cotton and 50 per cent.
of nitro-glycerine. As nitro-glycerine will not dissolve its own weight of
nitro-cotton (even the soluble variety), benzol is used as a solvent, but
is afterwards removed from the finished product, just as the acetone is
removed from cordite. About 1 per cent. of diphenylamine is added for the
purpose of increasing its stability.
The colour of ballistite is a darkish brown. It burns in layers when
ignited, and emits sparks. The size of the cubes into which it is cut is a
0.2-inch cube. Its density is 1.6. It is also, by means of a special
machine, prepared in the form of sheets, after being mixed in a wooden
trough fitted with double zinc plates, and subjected to the heating
process by means of hot-water pipes. It is passed between hot rollers, and
rolled into sheets, which are afterwards put through a cutting machine and
granulated. Sir A. Nobel's experiments[A] with this powder gave the
following results:--The charge used was 5 lbs. 8 oz., the size of the
cubes being 0.2 inch. The mean crusher-gauge pressure was 14.3 tons per
square inch (maximum, 2,210; minimum, 2,142), and average pressure 2,180
atmospheres. The muzzle velocity was 2,140 foot seconds, and the muzzle
energy 1,429 foot tons. A gramme of ballistite generates 615 c.c. of
permanent gases, and gives rise to 1,365 grm. units of heat. Ballistite is
manufactured at Ardeer in Scotland, at Chilworth in Surrey, and also in
Italy, under the name of Filite, which is in the form of cords instead of
cubes. The ballistite made in Germany contained more nitro-cellulose, and
the finished powder was coated with graphite. Its use has been
discontinued as the Service powder in Germany, but it is still the Service
powder in Italy.
[Footnote A: _Proc. Roy. Soc._, vol. lii., p. 315.]
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