Nitro-Explosives: A Practical TreatiseSanford, P. Gerald (Percy Gerald)
Science
Nitro-Explosives: A Practical Treatise
Sanford, P. Gerald (Percy Gerald)
Celluloid; Explosives
~U.S. Naval Smokeless Powder.~--This powder is manufactured at the U.S.
Naval Torpedo Station for use in guns of all calibres in the U.S. Navy. It
is a nitro-cellulose powder, a mixture of insoluble and soluble nitro-
cellulose together with the nitrates of barium and potassium, and a small
percentage of calcium carbonate. The proportions in the case of the powder
for the 6-inch rapid-fire gun are as follows:--Mixed nitro-cellulose
(soluble and insoluble) 80 parts, barium nitrate 15 parts, potassium
nitrate 4 parts, and calcium carbonate 1 part. The percentage of nitrogen
contained in the insoluble nitro-cellulose must be 13.30+-0.15, and in the
soluble 11.60+-0.15, and the mean nitration strength of the mixture must be
12.75 per cent. of nitrogen. The solvent used in making the powder is a
mixture of ether (sp. gr. 0.720) 2 parts, and alcohol (95 per cent. by
volume) 1 part. The process of manufacture is briefly as follows:[A]--The
soluble and insoluble nitro-cellulose are dried separately at a
temperature from 38 deg. to 41 deg. C., until they do not contain more than 0.1
per cent. of moisture. The calcium carbonate is also finely pulverised and
dried, and is added to the mixed nitro-celluloses after they have been
sifted through a 16-mesh sieve. The nitrates are next weighed out and
dissolved in hot water, and to this solution is added the mixture of
nitro-celluloses and calcium carbonate with constant stirring until the
entire mass becomes a homogeneous paste. This pasty mass is next spread
upon trays and re-dried at a temperature between 38 deg. and 48 deg. C., and when
thoroughly dry it is transferred to the kneading machine. The ether-
alcohol mixture is now added, and the process of kneading begun. It has
been found by experiment that the amount of solvent required to secure
thorough incorporation is about 500 c.c. to each 500 grms. of dried paste.
To prevent loss of solvent due to evaporation, the kneading machine is
made vapour light. The mixing or kneading is continued until the resulting
greyish-yellow paste is absolutely homogeneous so far as can be detected
by the eye, which requires from three to four hours. The paste is next
treated in a preliminary press (known as the block press and is actuated
by hydraulic power), where it is pressed into a cylindrical mass of
uniform density and of such dimensions as to fit it for the final or
powder press. The cylindrical masses from the block press are transferred
to the final press, whence they are forced out of a die under a pressure
of about 500 lbs. per square inch. As it emerges from the final press the
powder is in the form of a ribbon or sheet, the width and thickness of
which is determined by the dimensions of the powder chamber of the gun in
which the powder is to be used. On the inner surface of the die are ribs
extending in the direction of the powder as it emerges from the press, the
object of these ribs being to score the sheets or ribbons in the direction
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