Nitro-Explosives: A Practical TreatiseSanford, P. Gerald (Percy Gerald)
Science
Nitro-Explosives: A Practical Treatise
Sanford, P. Gerald (Percy Gerald)
Celluloid; Explosives
~Properties of Gun-Cotton.~--The absolute density of gun-cotton is 1.5.
When in lumps its apparent density is 0.1; if twisted into thread, 0.25;
when subjected, in the form of pulp, to hydraulic pressure, 1.0 to 1.4.
Gun-cotton preserves the appearance of the cotton from which it is made.
It is, however, harsher to the touch; it is only slightly hygroscopic (dry
gun-cotton absorbs 2 per cent. of moisture from the air). It possesses the
property of becoming electrified by friction. It is soluble in acetic
ether, amyl acetate, and acetone, insoluble in water, alcohol, ether,
ether-alcohol, methyl-alcohol, &c. It is very explosive, and is ignited by
contact with an ignited body, or by shock, or when it is raised to a
temperature of 172 deg. C. It burns with a yellowish flame, almost without
smoke, and leaves little or no residue. The volume of the gases formed is
large, and consists of carbonic acid, carbonic oxide, nitrogen, and water
gas. Compressed gun-cotton when ignited often explodes when previously
heated to 100 deg. C.
Gun-cotton kept at 80 deg. to 100 deg. C. decomposes slowly, and sunlight causes
it to undergo a slow decomposition. It can, however, be preserved for
years without undergoing any alteration. It is very susceptible to
explosions by influence. For instance, a torpedo, even placed at a long
distance, may explode a line of torpedoes charged with gun-cotton. The
velocity of the propagation of the explosion in metallic tubes filled with
pulverised gun-cotton has been found to be from 5,000 to 6,000 mms. per
second in tin tubes, and 4,000 in leaden tubes (Sebert).
Gun-cotton loosely exposed in the open air burns eight times as quickly as
powder (Piobert). A thin disc of gun-cotton may be fired into from a rifle
without explosion; but if the thickness of the disc be increased, an
explosion may occur. The effect of gun-cotton in mines is very nearly the
same as that of dynamite for equal weights. It requires, however, a
stronger detonator, and it gives rise to a larger quantity of carbonic
oxide gas. Gun-cotton should be neutral to litmus, and should stand the
Government heat test--temperature of 150 deg. F. for fifteen minutes (see page
249). In the French Navy gun-cotton is submitted to a heat test of 65 deg. C.
(= 149 deg. F.) for eleven minutes. It should contain as small a percentage of
soluble nitro-cotton and of non-nitrated cotton as possible.
The products of perfectly detonated gun-cotton may be expressed by the
following equation:--
2C_{12}H_{14}O_{4}(NO_{3})_{6} = 18CO + 6CO_{2} + 14H_{2}O + 12N.
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