Nitro-Explosives: A Practical Treatise — John Shaqi
Nitro-Explosives: A Practical TreatiseSanford, P. Gerald (Percy Gerald)
Science
Nitro-Explosives: A Practical Treatise
Sanford, P. Gerald (Percy Gerald)
Celluloid; Explosives
In the process above described, the object of the introduction of a small
layer of sulphuric acid is mainly to prevent the fuming which would
otherwise take place, and is not essential, as it is found it can be
omitted without any deleterious effect. In order to use the mixed acids in
the most economical manner, the waste acid from a previous operation may
be used for a first nitration of the cellulose; being afterwards displaced
with fresh acids which carry the nitration to the required degree before
they are in turn displaced by water. The apparatus may be used merely for
the removal of the acid, in which case the nitration is carried out in
other vessels in the usual way, and the nitro-cellulose removed to the
displacement apparatus where it is just covered with waste acid, and the
displacement then proceeded with as above described. In some cases the
process is carried out in an ordinary nitrating centrifugal, using the
latter to effect preliminary drying after acid extraction. This gives a
great advantage over the usual method of working ordinary centrifugal
nitrating apparatus, because the acid being removed before the centrifugal
is run, practically all danger of firing therein disappears, and a greater
proportion of the waste acid is recovered.
In some cases the acids and water may be supplied by perforated pipes,
lying along the edges of the nitrating vessel, and these edges may, if
desired, be themselves made inclined, like the sides of the troughs _f_.
In the case of effecting nitration in centrifugals as above, the
displacing sulphuric acid and water may thus be supplied round the edges
of the machines, or removal troughs such as _f_ may be used. It will be
obvious that any inert liquid of suitable specific gravity may be used
instead of sulphuric acid, as a separation layer.
~Moulding.~--By means of the small measuring tank above referred to, the
gun-cotton pulp is drawn off from the stuff chest, and run into moulds of
the shapes and sizes required. Thence a large proportion of the water is
drawn off by means of tubes connected with the vacuum engine, the moulds
having bottoms of fine wire gauze, in order to prevent the pulp from
passing through. Hydraulic pressure of about 34 lbs. on the square inch is
then applied, which has the effect of compressing the pulp into a state in
which it has sufficient consistency to enable it to be handled with care,
and also expels a portion of the remaining water.
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