Nitro-Explosives: A Practical TreatiseSanford, P. Gerald (Percy Gerald)
Science
Nitro-Explosives: A Practical Treatise
Sanford, P. Gerald (Percy Gerald)
Celluloid; Explosives
~Granulation of Gun-Cotton.~--Gun-cotton is often required in the
granulated form for use either alone or with some form of smokeless
powder. This is done under the patent of Sir Frederick Abel in the
following manner:--The gun-cotton from the poacher is placed in a
centrifugal machine, very similar to the hydro-extractors before
mentioned, and used for wringing out the acids. In this machine it loses
water until it only contains 33 per cent., and is at the same time reduced
to a more or less fibrous state. It is then taken to the granulating room,
where it is first passed through sieves or perforations, which break up
the mass into little pieces like shot. The material is then transferred to
a revolving drum made of wood or stout leather, which is kept constantly
revolving for some time. The material is occasionally sprinkled with
water. The drum in turning, of course, carries the granules partially
round with it, but the action of gravity causes them to descend constantly
to the lowest point, and thus to roll over one another continually. The
speed of the drum must not be too rapid. None of the granules must be
carried round by centrifugal force, but it must be fast enough to carry
them some little distance up the side of the drum. After removal from the
drum the granules are dried upon shelves in the drying house.
Gun-cotton is also dissolved in acetone or acetic ether until it has taken
the form of a jelly. It is then rolled into thin sheets, and when dry cut
up into little squares. In the manufacture of smokeless powders from
nitro-cellulose, nitro-lignine, &c., the various substances are mixed with
the gun-cotton or collodion-cotton before granulating.
~Collodion-Cotton.~--In the manufacture of collodion or soluble cotton the
finer qualities of cotton-waste are used and the acids used in the dipping
tanks are much weaker. The manufacture of collodion-cotton has become of
more importance than gun-cotton, by reason of its use for the manufacture
of the various forms of gelatine, such as gelatine dynamite, gelignite,
forcite, &c., and also on account of its extensive use in the manufacture
of many of the smokeless powders. It is also used for the manufacture of
"collodion," which is a solution of collodion-cotton in ether-alcohol; for
the preparation of celluloid, and many other purposes. It is less
explosive than gun-cotton, and consists of the lower nitrates of
cellulose. It is soluble in nitro-glycerine, and in a mixture of 2 parts
of ether and 1 of alcohol; also in acetone, acetic ether, and other
solvents. MM. Menard and Domonte were the first to prepare a soluble gun-
cotton, and its investigation was carried on by Bechamp, who showed that
its properties and composition were different to those of gun-cotton.
Public-domain text, read in full here on John Shaqi.
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