Nitro-Explosives: A Practical TreatiseSanford, P. Gerald (Percy Gerald)
Science
Nitro-Explosives: A Practical Treatise
Sanford, P. Gerald (Percy Gerald)
Celluloid; Explosives
Nitro-starch has also been used for the manufacture of an explosive.
Muhlhauer has described (_Ding. Poly. Jour._, 73, 137-143) three nitric
ethers of starch, the tetra-nitro-starch, C_{12}H_{16}O_{6}(ONO_{2})_{4},
the penta- and hexa-nitro-starch. They are formed by acting upon potato
starch dried at 100 deg. C. with a mixture of nitric and sulphuric acids at a
temperature of 20 deg. to 25 deg. C. Rice starch has also been used in its
production. Muhlhauer proposes to use this body as a smokeless powder, and
to nitrate it with the spent mixed acids from the manufacture of nitro-
glycerine. This substance contains from 10.96 to 11.09 per cent. of
nitrogen. It is a white substance, very stable and soluble even in cold
nitro-glycerine.
The explosive bodies formed by the nitration of jute have been studied by
Messrs Cross and Bevan. and also by Muehlhaeuer. The former chemists give
jute the formula C_{12}H_{18}O_{9}, and believe that its conversion into a
nitro-compound takes place according to the equation--
C_{12}H_{18}O_{9} + 3HNO_{3} = 3H_{2}O + C_{12}H_{15}O_(6}(NO_{3})_{3}.
This is equivalent to a gain in weight of 44 per cent. for the tri-
nitrate, and 58 per cent. for the tetra-nitrate. The formation of the
tetra-nitrate appears to be the limit of nitration of jute fibre. Messrs
Cross and Bevan say, "In other words, if we represent the ligno-cellulose
molecule by a C_{12} formula, it will contain four hydroxyl (OH) groups,
or two less than cellulose similarly represented." It contains 11.5 per
cent. of nitrogen. The jute nitrates resemble those of cellulose, and are
in all essential points nitrates of ligno-cellulose.
Nitro-jute is used in the composition of the well-known Cooppal Smokeless
Powders. Cross and Bevan are of opinion that there is no very obvious
advantage in the use of lignified textile fibres as raw materials for
explosive nitrates, seeing that a number of raw materials containing
cellulose (chiefly as cotton) can be obtained at from L10 to L25 a ton,
and yield also 150 to 170 per cent. of explosive material when nitrated
(whereas jute only gives 154.4 per cent.), and are in many ways superior
to the products obtained from jute. Nitro-lignin, or nitrated wood, is,
however, largely used in the composition of a good many of the smokeless
powders, such as Schultze's, the Smokeless Powder Co.'s products, and
others.
Public-domain text, read in full here on John Shaqi.
Reviews
Reviews
No reviews yet
Be the first to share your thoughts on this work.
Join the Discussion
Join the discussion
Sign in to leave a comment or review.
Sign InorCreate an account