Non-technical chats on iron and steel, and their application to modern industrySpring, La Verne W. (La Verne Ward)
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Non-technical chats on iron and steel, and their application to modern industry
Spring, La Verne W. (La Verne Ward)
Iron; Steel
Of the iron-carbon alloys of compositions lying to the right of the line
UV, we find the case to be different, for each one of them has more than
the 1.7% of carbon which is the maximum amount which “gamma” iron can
retain. Now the lowest temperature at which any iron-carbon alloy can
exist without freezing is slightly above 2066° F., and there is but one
composition—95.7% of iron and 4.3% of carbon—which can survive until
_this_ low temperature is reached. A content of 4.3% of carbon then, is
the greatest and also the least concentration which Nature will allow to
remain molten down to this minimum temperature. This 4.3% carbon
composition which is the lowest melting, i.e., the easiest melted alloy,
is called the “eutectic” alloy from Greek words which mean “well
melting.” This eutectic composition may be said to divide or rather
subdivide this group of alloys into two groups, those containing between
1.7% and 4.3% of carbon, and those which have 4.3% and over.
As stated before, freezing is not an instantaneous but a progressive
process. During the freezing period of any of these alloys which have
over 1.7% of carbon the _still liquid portion_ which remains after
freezing begins to become smaller and smaller in quantity as freezing
progresses just as it did in alloys of the “_solid solution_” group. And
as Nature allows a concentration of 4.3% of carbon as the highest
concentration at the minimum temperature the very last of the remaining
liquid of every alloy eventually gets to this eutectic composition just
before the alloy freezes. Those to the left of the eutectic or exact
4.3% composition do so by the gradual freezing out of iron containing
the maximum or 1.7% of carbon, i.e., iron is taken out faster than
carbon, hence there is gradual concentration of carbon in the remaining
liquid. This goes on until 4.3% is reached. The compositions to the
right of the line WX throw out the chemical compound, Fe_{3}C, which
contains 6.6% of carbon, whereby carbon is eliminated faster than iron
and the desired 4.3% carbon alloy is arrived at from the other
direction.
To illustrate, take, say, the composition represented by the vertical
line at 3% carbon and 97% iron. As the molten alloy cools it reaches the
temperature 2330° F., at which temperature the vertical line
representing the 3% carbon composition cuts the line AB. Here the alloy
begins to freeze by the separation of small crystals of solidifying iron
containing definite amounts of carbon.[11] But as the carbon thus taken
along by the freezing crystals of iron is always less than 1.7%, a
proportionally greater amount of iron than carbon is removed from the
unfrozen part of the alloy and the remaining liquid or unfrozen part,
therefore, is left with slightly more than the 3% of carbon with which
it started.
Footnote 11:
Public-domain text, read in full here on John Shaqi.
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