Non-technical chats on iron and steel, and their application to modern industrySpring, La Verne W. (La Verne Ward)
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Non-technical chats on iron and steel, and their application to modern industry
Spring, La Verne W. (La Verne Ward)
Iron; Steel
The percentages of carbon carried by the particles of iron freezing at
any particular temperature of the solidification range may be
determined from the diagram but the works named in the reference list
should be consulted for method and explanation.
This we must now consider another alloy with a lower freezing-point, the
reason being, of course, its higher carbon content. At the next lower
temperature, more iron containing carbon is frozen out and the remaining
liquid is again left a little higher in carbon than before. In this way
the continually diminishing amount of remaining liquid keeps
concentrating, forming thereby a continuous succession of alloys of
higher and higher carbon content as the temperature continuously drops.
Eventually, of course, the concentration of this remaining liquor
becomes 4.3% of carbon just before completion of the freezing at 2066°
F.
[Illustration:
THE “EUTECTIC,” THE PART OF THE ALLOY WHICH SOLIDIFIES LAST
(_Magnification 700 Diameters_)
]
Now with alloys containing more than 4.3% of carbon, almost the opposite
occurs. Let us choose the one having 5% carbon and 95% of iron. This
molten alloy cools until at 2215° F., small crystals begin to freeze and
form in the molten mass. But, as the liquid already has more than the
favored 4.3% of carbon, it is not free iron which freezes out, but
instead, the chemical compound, Fe_{3}C, which contains 6.6% of carbon.
This, of course, takes out carbon proportionally faster than iron,
hence, at each very slightly lower temperature, the liquid which remains
unfrozen contains just a little less of carbon than did its predecessor.
So the constantly decreasing amount of remaining liquid progresses
through a succession of compositions each containing just a little less
of carbon than the previous one, and eventually, just before freezing we
get back to the mixture which contains 4.3% of carbon. Of course there
is left unfrozen by this time only a very small amount of the alloy and
it is this which has the composition stated.
The “Eutectic”
Now, having just the composition which she wants, whether arrived at
from alloys lower or higher than 4.3% in carbon, Nature lets this
composition freeze at once in thin alternating plates which lie side by
side about and among the earlier frozen crystals of the alloy. The
appearance of this typical eutectic formation under the microscope is
shown on page 341.
Had we chosen the 4.3% alloy itself, neither any of the solid solution
of carbon in iron nor the chemical compound, Fe_{3}C, would have frozen
out, but the whole mass would have remained liquid down to 2066° F.,
where the whole would have solidified at once in the plate-like eutectic
formation just described.
Public-domain text, read in full here on John Shaqi.
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