Non-technical chats on iron and steel, and their application to modern industrySpring, La Verne W. (La Verne Ward)
History
Non-technical chats on iron and steel, and their application to modern industry
Spring, La Verne W. (La Verne Ward)
Iron; Steel
But for the moment considering only the steels, i.e., the third of the
diagram to the left of the 1.7% carbon line, we remember that upon
completion of the solidification of any alloy, we had only a frozen
solution of all the carbon in iron. Now in the bottom part of this left
third of our diagram on page 344, the line GOSE does not look so very
much different than the freezing line, ABC, does it? It resembles it not
only in appearance but also in actual experience. But in this case it
represents not a freezing from liquid to solid but a decomposition, or
better perhaps, a transformation. The solid solutions or alloys which
contain less than .9% of carbon give up their excess of pure iron upon
getting down to temperatures lying along the line GOS, by gradual
decomposition of the austenite. In alloys lying to the right of this .9%
carbon vertical line the austenite rids itself of excess carbon by
throwing out of solid solution and freeing the chemical compound,
Fe_{3}C, as the line SE is reached and passed. That is, analogously to
what occurred during freezing, certain concentrations occur in the
_solid_, lower carbon alloys by gradual rejection of pure iron crystals
until the remainder of the mass has exactly .9% of carbon, or
_deconcentrate_ in the higher ones by rejection of Fe_{3}C until they
reduce the carbon to this .9% figure. In all cases, by the time the
temperature 1290° F., has been reached this has been accomplished and
the remaining undecomposed austenite, now with just .9% of carbon, in
some way splits into the alternating plate-like constituent which is
shown in the cut on page 341.
[Illustration:
THE EQUILIBRIUM DIAGRAM AND INTERPRETATION AS NOW TENTATIVELY ACCEPTED
]
This plate-like constituent we can hardly call eutectic or
“well-melting” alloy for it, as well as the rest of the alloy, has been
solid for a long time. But being so similar in derivation and appearance
to the eutectic which forms during freezing of a molten alloy, it is
proposed that it be called the next best thing, the “eutectoid.” It is
often called the eutectic, however.
By this time you doubtless have seen that the free iron which was thrown
out of the steel having less than .9% carbon is the ferrite which we
found in the soft steels, and that the chemical compound, Fe_{3}C, of
the higher carbon steels is the extremely hard constituent, cementite.
The eutectoid or plate-like structure is, of course, pearlite, which in
the last chapter we found to consist of just these alternating plates of
ferrite and cementite.
The Cast Irons
All of the alloys lying to the right of the line UV contain more than
1.7% of carbon, and, according to our classification, therefore, are
“cast irons.”
Public-domain text, read in full here on John Shaqi.
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