Non-technical chats on iron and steel, and their application to modern industrySpring, La Verne W. (La Verne Ward)
History
Non-technical chats on iron and steel, and their application to modern industry
Spring, La Verne W. (La Verne Ward)
Iron; Steel
To sum up, iron-carbon alloys which contain less than 1.7% of carbon, in
other words, the steels, freeze as solid solutions of carbon in gamma
iron. This, of course, is the metallographic constituent which is called
austenite. It is not of a definite composition as it contains whatever
carbon is available up to 1.7%. Alloys containing between 1.7% and 4.3%
of carbon gradually freeze out this solid solution, austenite, more and
more being formed in the freezing alloy until, upon arriving at a
concentration of 4.3% of carbon for the remaining liquid, the latter,
too, freezes as a eutectic of alternating plates of more of this same
constituent, austenite, and the carbide of iron, Fe_{3}C, about and
among the crystals of the previously formed austenite. From alloys which
contain more than 4.3% of carbon, iron carbide, Fe_{3}C, gradually
freezes out as the temperature falls, until, at concentration of 4.3% of
carbon, the eutectic of remaining carbide and austenite forms about and
among the earlier frozen carbide crystals, always at the same
temperature, 2066° F., no matter what the original composition of the
alloy.
Upon reheating, the constituents melt in reverse order, the eutectic
liquifying first at 2066° F., the remainder of the alloy gradually
becoming liquid between this temperature and the temperature at which
the first freezing began during cooling.
Transformations and Decompositions
So far we have considered only the freezing of the iron-carbon alloys
from the molten to the solid condition. Now what happens to them at
temperatures below 2066° F.? Do they remain as we left them above, until
and after they are fully cold?
We must now combine the little sketch which we made on page 319, by
plotting the points, Ar_{1}, Ar_{2} and Ar_{3}, with the freezing-point
diagram which we have just now been considering. You remember that we
found all sorts of things happening to our 0% to 1.7% alloys—the
steels—at temperatures around 1290° F., 1395° F., and 1650° F.
Similarly, a great deal happens to these other alloys, as they cool from
their solidifying temperatures downward.
[Illustration:
THE FREEZING-POINT AND CRITICAL-POINT CURVES MAKE UP THE EQUILIBRIUM
DIAGRAM
]
Public-domain text, read in full here on John Shaqi.
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