Next to the fossil fuels, the most important products of the rocks in
North America are the iron ores. Although certain igneous rocks are rich
in iron, and in some instances contain it even in a pure or
metallic state, none of the rocks that have cooled from fusion carry
iron in any form in sufficient quantities to be of commercial
importance. Most of the iron in igneous rocks is contained in mineral,
usually silicates, and would be difficult to separate. When exposed to
the air and to percolating water, the iron-bearing minerals of the
igneous or other rocks decay and the iron enters into various new
combinations. When organic acids are present, and especially carbon
dioxide, ferrous carbonate is formed, which is quite soluble, and is
taken into solution by percolating water, some of which emerges as
springs, and joins the surface run-off, which may also take up ferrous
carbonate in solution. One of the most common methods by which iron ore
is accumulated is when water carrying ferrous carbonate in solution
forms swamps and lakes, and in many instances as the water is exposed to
the air and aided by evaporation it parts with a portion of its carbon
dioxide, and the hydrated sesquioxide of iron or limonite results. When,
under similar conditions, an excess of organic matter is present, beds
of ferrous carbonate are formed. In other instances iron oxide is
precipitated in swamps and lakes through the action of low forms of
plant life. The ores of iron concentrated in these ways are in many
instances in well-defined layers, or lenticular bodies, which are
thickest in the central portion and thin out in all directions. Their
forms are determined mainly by the shapes of the depressions they
occupy. Both ferrous carbonate and limonite, however, occur in irregular
surface deposits.
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