In North America, bog-iron ores occur at the surface in many regions, in
existing swamps and about springs, but are seldom of economic
importance, owing in part to the great abundance of better ores.
Limonite occurs at the surface also, having been deposited in cavities
and as a cement for loose fragments, particularly on the weathered
outcrops of formations rich in iron. When rocks contain but a fraction
of 1 per cent of iron, the soil on their weathered outcrops, owing to
the removal of the more soluble ingredients and the leaving of the less
soluble oxidized iron, have a yellow, brown, or red colour, and
in some instances this process of concentration has produced workable
iron ore. Limonite and earthy hematites occur widely throughout the
Appalachian region, in central New York, and westward to the Mississippi
Valley. One of the most productive formations is the Clinton, a division
of the Silurian, the outcrop of which extends in a nearly continuous
band from Alabama, where at Birmingham, etc., it is extensively worked,
northward along the west side of the Appalachians to central New York,
and thence westward to Ohio, and appears again in Wisconsin. At many
localities throughout this belt, some 1,300 miles in length, iron
furnaces have been built, although now mostly abandoned, the ore supply
being the weathered outcrop of the Clinton limestone.
In the Carboniferous rocks of Pennsylvania and neighbouring States to
the south and west, layers of ferrous carbonate, formed when there was
an excess of organic matter present, termed black-band ore and kidney
ore, occur. The former is present as regular strata and the latter in
oval concretionary masses. These ores, although not as rich in iron and
less pure than certain other and more abundant and more accessible
deposits, have been extensively utilized, largely for the reason that
they occur in the same formation which furnishes coal available for
their reduction.
Deposits of iron ore accumulated in the several ways referred to above
may be metamorphosed and changed to hematite and magnetite. The richest
iron ores of North America are of this nature, and will be referred to
below in connection with other substances of economic importance
contained in the metamorphic rocks.
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