Notes and Queries, Number 226, February 25, 1854: A Medium of Inter-communication for Literary Men, Artists, Antiquaries, Genealogists, etc. — John Shaqi
Notes and Queries, Number 226, February 25, 1854: A Medium of Inter-communication for Literary Men, Artists, Antiquaries, Genealogists, etc.Various
History
Notes and Queries, Number 226, February 25, 1854: A Medium of Inter-communication for Literary Men, Artists, Antiquaries, Genealogists, etc.
Various
Questions and answers -- Periodicals
_Test for Nitrate of Silver._--The READER OF PHOTOGRAPHIC WORKS, who in
Vol. ix., p. 111., asked for information as to how he might know whether
nitrate of silver was pure, can detect any impurities with which that salt
is likely to be contaminated, by applying a few simple tests to an aqueous
solution of it. The impurities which nitrate of silver most frequently
contains are nitrate of copper, nitrate of potash, and free nitric acid. It
is also sometimes intentionally adulterated with nitrate of lead. The
presence of a salt of copper is detected by the solution assuming a blue
colour when mixed with an excess of ammonia. To detect nitrate of potash,
hydrochloric acid should be added to the solution in sufficient quantity to
precipitate the whole of the silver. The liquid should then be freed from
the precipitate by filtration, and evaporated; if nitrate of potash is
present, a fixed residue will remain after evaporation. The presence of a
salt of lead is detected by adding a few drops of sulphuric acid to the
solution of nitrate of silver, which precipitates the lead as sulphate if
present. It is, however, necessary to dilute the acid with a considerable
quantity of water, and, if any precipitate forms, to allow it to subside
previous to using it as a test for lead, as ordinary sulphuric acid is
frequently contaminated with sulphate of lead, which is soluble in the
strong, but not in dilute, acid.
Any free nitric acid in the nitrate of silver can be detected by the smell.
The crystals can be freed from {182} it, should they contain any, by fusing
them in a porcelain crucible over a spirit-lamp. The ordinary fused lunar
caustic of the surgeon is unfit for general use as a photographic agent.
J. LEACHMAN.
_Professor Hunt's Photographic Studies._--My attention has just been
directed to a "Practical Photographic Query" in your Journal, Vol. ix., p.
41., which appears to require a reply from me. It is quite evident that
your correspondent, notwithstanding the personal respect which he professes
to entertain, cannot have any intimate knowledge of either my works or my
studies. Allow me to make my position clear to him and other of your
readers. My first photographic experiment dates from January 28, 1839, and
since that period the investigation of the _chemical phenomena of the solar
rays_ has been the constant employment of all the leisure which a busy life
has afforded me. The production of photographic pictures has never been the
ultimate object at which I have aimed, although my researches have caused
me to obtain thousands. My object has been, and is, to endeavour to obtain
some light into the mysteries of the radiant force with which the
photographic artist works, being quite content to leave the production of
beautiful images to other manipulators.
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