The old Saxon blue or simple solution of indigo with sulphuric acid is
now seldom prepared by the manufacturers themselves. It is now
generally prepared for them, and furnished commercially under the name
of _indigo extract_. The finer qualities used for fine dyeing and
printing are known under the name of _carmines_ of indigo, _neutral
extract_, _soluble indigo_, _ceruline_, &c.
The production of indigo carmines, which are simply alkaline
sulphindigotates or sulpho-purpurates, is founded upon their
insolubility in a liquid charged with a salt.
If, for example, we dissolve one part of indigo in four parts of
fuming acid, and dilute the liquid with sixty or eighty times its
weight of water, it will contain, besides the _sulphindigotic_ acid,
an excess of sulphuric acid. By adding one part of crystals of soda so
as to neutralize the bath, there will be formed not only
sulphindigotate of soda, but sulphate of soda: as the former is
insoluble in the saline liquid, the presence of the sulphate of soda
causes the precipitation of the sulphindigotate in deep blue
floccules. These are collected on woollen filters and washed to remove
the sulphate of soda and a green coloring material, probably a
modified chlorophyl, which the paste often contains, and which has the
singular property of fixing itself on silk, but not on wool.
The carmines are divided according to their richness in indigo into
simple carmine (4.96 per cent of indigo, water 89, saline materials
57), double carmine (10.2 per cent indigo, water 85, salts 4–8),
triple carmine (12.4 per cent indigo water, 73.7, salts 13.9). A
species of solid carmine known as Boiley blue or purple is in high
repute in France.
The carmines may be tested by dyeing a specimen of wool in an
acidulated bath to which cream of tartar has been added. The presence
of the green matter, so objectionable to silk-dyers who make much use
of these carmines, is detected by rubbing a small quantity of the
carmine on a piece of glazed paper, which, when the color dries, gives
a color varying from blue to a rich copper color: if any green
coloring matter is left, it shows itself by a green aureola around the
blue color. The method of applying the carmines in dyeing wool and
silk,—for they are not adapted to cotton fabrics,—as given by M. de
Kæppelin, is as follows:—
The operation is conducted in small wooden vats, provided with
openings for manipulation, and pipes for inducting steam to heat the
baths to the proper temperature. It consists of two parts, that of
mordanting and dyeing. The former is thus conducted.
Public-domain text, read in full here on John Shaqi.
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