Novum organon renovatum: Being the second part of the philosophy of the inductive sciencesWhewell, William
Philosophy
Novum organon renovatum: Being the second part of the philosophy of the inductive sciences
Whewell, William
Science -- Philosophy
Not only, however, was the hypothesis of primitive forms and
decrements untenable, but this notation was too unsystematic to
stand long. And when Weiss and Mohs established the distinction of
Systems of Crystallography[66\4], they naturally founded upon that
distinction a notation for crystalline forms. Mohs had several
followers; but his algebraical notation so barbarously violated all
algebraical meaning, that it was not likely to last. Thus, from a
primitive rhombohedron which he designated by _R_, he derived, by a
certain process, a series of other rhombohedrons, which he denoted
by _R_ + 1, _R_ + 2, _R_ − 1, &c.; and then, by another mode of
derivation from them, he obtained forms which he marked as
(_R_ + 2)², (_R_ + 2)³, &c. In doing this he used the algebraical
marks of addition and involution without the smallest ground;
besides many other proposals no less transgressing mathematical
analogy and simplicity.
[Note 66\4: _Hist. Ind. Sc._ b. xv. c. 4.]
But this notation might easily suggest a better. If we take a
primitive form, we can generally, by two steps of derivation, each
capable of numerical measure, obtain any possible face; and
therefore any crystalline form bounded by such faces. Hence all that
we need indicate in our crystalline laws is the primitive form, and
two numerical exponents; and rejecting all superfluity in our
symbols, instead of (_R_ + 2)³ we might write 2 _R_ 3. Nearly of
this kind is the notation of Naumann. The systems of
crystallization, the octahedral or tessular, the rhombic, and the
prismatic, are marked by the letters _O_, _R_, _P_; and from these
are derived, by certain laws, such symbols as
3 _O_ ½, ∞ _R_ 2, ½ _P_ 2, {359}
which have their definite signification flowing from the rules of
the notation.
But Professor Miller, who has treated the subject of Crystallography
in the most general and symmetrical manner, adopts the plan of
marking each crystalline plane by _three_ numerical indices. Thus in
the Octahedral System, the cube is {100}; the octahedron is {111};
the rhombic dodecahedron is {011}; the pentagonal dodecahedron is π
{012}; where π indicates that the form is not _holohedral_ but
_hemihedral_, only half the number of faces being taken which the
law of derivation would give. This system is the most mathematically
consistent, and affords the best means of calculation, as Professor
Miller has shown; but there appears to be in it this defect, that
though an essential part of the scheme is the division of
crystalline forms into Systems,--the Octahedral, Pyramidal,
Rhombohedral and Prismatic,--this division does not at all appear in
the notation.
But whatever be the notation which the crystallographer adopts, it
is evident that he must employ some notation; and that, without it,
he will be unable to express the forms and relations of forms with
which he has to deal.
2. CHEMISTRY.
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