Many fragments of the meteorite iron have been found around the crater,
and it is reasonable to assume that this is the kind of iron we would
expect to find in the core of the earth. Like the core iron, it is mixed
with a little lead, which can be isolated and analyzed in a mass
spectrometer for its isotopic composition. This lead is found to be much
less contaminated with radiogenic lead, and hence is much more primitive
than the oldest leads found on earth. Thus, meteorites presumably are as
close as we can get to true primordial lead—the lead of the time when
the earth (and the protoplanet) first formed.
Once these measurements were available, it was easy to write the
Houtermans equation for present-day and primordial leads in this way:
((²⁰⁶Pb)/(²⁰⁴Pb)) present - ((²⁰⁶Pb)/(²⁰⁴Pb)) primordial
------------------------ --------------------------
((²⁰⁷Pb)/(²⁰⁴Pb)) present - ((²⁰⁷Pb)/(²⁰⁴Pb)) primordial
= 137.7 ((e^{λ}238^{t} - 1))/((e^{λ}235^{t} - 1))
The present ratio of ²³⁸U to ²³⁵U is 137.7.
e = the base of natural logarithms
λ = the DECAY CONSTANT of each isotope of uranium
t = the age of the earth.
Substituting the best experimental lead isotope ratios into the equation
and solving for t, Patterson was able to calculate that the earth is
4550 million years (4.55 aeons) old. Subsequent calculations based on
other procedures generally have confirmed that result.
Analytical Techniques
Each method of nuclear age determination involves a different sequence
of sample preparation. Wood, peat, charcoal, bones, or shells are
cleaned for carbon-14 dating in order to remove every trace of possible
contamination by modern carbon as well as extraneous old carbon. Rocks
are crushed and ground, minerals are separated according to what is
needed in any particular study, and the desired elements are extracted
and separated by chemical procedures. Often there may be several
different ways of doing the same thing; different laboratories use
different procedures. In every case, however, long and complicated
procedures must be followed before results are obtained from which an
age can be calculated. There is no such thing as a black box into which
you can throw a rock and read its age on a dial!
Of all the elements that are part of the useful parent-daughter systems,
only potassium is common enough to be analyzed by conventional chemical
techniques. All the other elements, especially the radiogenic ones, are
present in such small quantities that special processes had to be
developed to measure them. The most valuable and generally used process
is called ISOTOPE DILUTION.
Isotope Dilution
This is a process for analyzing an unknown material by incorporating
uniformly into it a small amount of a radioactive test substance and
determining how much the tracer radioactivity is altered by dilution in
the original material.
Public-domain text, read in full here on John Shaqi.
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