An alternative method is to introduce the sample material into the
vacuum chamber in the form of a gas (like argon, for example), and then
bombard the gas with electrons streaming from a hot filament. The
electron stream will knock some electrons off the gas molecules and this
also will produce positive ions. Either process of ion production is
satisfactory, depending on the problem to be tackled, but the mass
spectrometers for the two methods are naturally quite different.
Whichever way the ions were produced, they are next exposed to a strong
electric field, accelerated, and electrostatically focused into a beam.
These charged particles are directed into a magnetic field between the
pole faces of an electromagnet. The magnet does the analyzing by the
principle of magnetic deflection that was known to André Ampere and
Michael Faraday more than a century ago. Any moving electric charge has
a magnetic field associated with it. This field interacts with the field
of the analyzing magnet to impress a deflecting force on the charge. The
force acts at right angles to the direction the charge travels and also
at right angles to the direction of the impressed magnetic field. The
pull of this force depends only on the electric charge and the speed of
each particle: A light single-charged particle will be deflected more
than a heavier particle with the same charge. In this way, the ions in
the beam are sorted out into a number of separate beams, each made up of
particles of the same charge/mass ratio. Each beam contains one isotope
of the original material, because isotopes differ on the basis of their
mass. By adjusting the current in the electromagnet we can direct these
separate beams into a “collector” and electrically measure their
intensity one by one. This gives the relative abundance of the separate
isotopes in the sample.
Minerals That Can Be Dated
Measuring age by one of the long-lived radioisotopes requires a closed
system. Usually this is some kind of crystal formed in a period of time
that is short, compared to the time that has elapsed since, and that has
remained unchanged since it formed. Specifically, neither the parent
isotopes can have been added nor the daughter isotopes removed by any
process other than radioactive decay.
The earth is a dynamic system, however. Things are always changing and
moving—not very rapidly, perhaps, but fast enough, in geologic time, to
raise mountains and shift oceans. Solutions are moving around,
dissolving something here and depositing it again somewhere else.
Temperatures are changing as one place is denuded by erosion and another
area buried under layers of sediment. Under such conditions, few systems
remain closed. It is perhaps surprising that we find any closed systems
at all. Let us look at a few that are known to be reliable. (They are
listed in Table I on page 4.)
Potash Feldspar
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