In spite of early disappointments with potash feldspar for argon dating,
some of it is useful for rubidium-strontium procedures. It all depends
on how much original strontium the potash feldspar contains. Most
feldspars, unfortunately, contain far too much, but rapid screening by
X-ray fluorescence or flame photometry methods can weed these out and
identify specimens low enough in original strontium to be useful.
Otherwise, feldspar is an excellent closed system for rubidium and
strontium; it remains closed even at temperatures high enough to melt
many other minerals. It is not affected at all by the same degree of
heating that will drive argon out of biotite. The rubidium-strontium age
of feldspar usually comes close to the time of original crystallization
of the rock.
Obviously, here is a geologically important tool. If we find feldspar
and biotite in one rock, and if feldspar, tested by the
rubidium-strontium method gives the same age as biotite tested by
potassium-argon decay, then we can say with confidence that the rock has
not been reheated since shortly after it crystallized. Conversely, if
the biotite comes out much younger than the feldspar, we can be sure
that something _has_ happened to this rock long after it first
crystallized. Such information is not only valuable to pure science—it
can also be useful in locating areas favorable for ore prospecting and
in other practical ways.
Zircon
Another very interesting mineral is zircon (a silicate of zirconium),
one of the accessory minerals found in small quantities in many
crystalline rocks. Zircon usually occurs in very small grains and is
heavy and hard, so that it can be separated from the other rock without
much difficulty, even though it may take 100 pounds of rock to supply a
gram of zircon.
Zircon usually contains a fair amount of uranium and very little lead.
It holds radiogenically produced lead well, even at relatively high
temperatures. But that is not all. Even if some of the lead is lost,
there is a mathematical way of correcting for it. This technique is
called CONCORDIA ANALYSIS and was developed by G. W. Wetherill, a
physicist then at the Carnegie Institution of Washington. It is based,
again, on the fact that natural uranium has two long-lived isotopes—²³⁸U
and ²³⁵U—and that the lighter one, ²³⁵U, decays faster than the heavier.
The daughter products of both uranium decay processes are isotopes of
the same element, lead—²⁰⁸Pb and ²⁰⁷Pb, respectively. Heavy isotopes are
not separated to any significant degree by chemical processes, so that
if radiogenic lead has been lost from a system for any reason, the other
lead isotopes also will have been lost in whatever proportion they were
present originally.
Public-domain text, read in full here on John Shaqi.
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