On adipocire, and its formationWetherill, Charles Mayer
Science
On adipocire, and its formation
Wetherill, Charles Mayer
Adipocere; Fatty acids; Postmortem changes
Specimens of this adipocire were presented to the Academy of Natural
Sciences, by my uncle, who found them at his country seat, opposite
Valley Forge, buried in moist ground, near a drain which led water from
a spring-house. About ten years previously, the shepherd in charge of a
flock of sheep indulged in a drunken spree, and in the meanwhile some
fifteen of the sheep in his care died from neglect, and were buried in
the above mentioned spot. My uncle, who was present at the exhumation
of the sheep, stated that in some of the remains, the exterior forms
of the muscles were very distinct. The two specimens I obtained were
in lumps, amorphous under the microscope, floating on water; of greasy
feel, and rank mutton smell, mingled with a peculiar disagreeable
fundamental smell, that I have observed in all my specimens of
adipocire, including the fossil one. Heated in a capsule with water,
a transparent fat floats melted on the surface; heated alone in a
platinum crucible, it melts and burns with a smoky flame, leaving a
slight residue, which effervesces with hydrochloric acid, and contains
beside sand and a little iron, principally lime. Under the microscope
with moderate powers, it is white, fatty, and granular, disappearing
with Canada balsam; with higher powers it is amorphous: melted on the
glass slide covered with thin glass, is crystalline on cooling, in
groups of plumose crystals, which give a beautiful play of colours
with polarized light; a drop of its weak alcoholic solution evaporated
spontaneously on glass gave the same appearance of crystallization.
Water added to this solution precipitated it in the form of a pure
white amorphous powder: distilled per se, leaves a slight carbonaceous
residue, and gives a volatile fat, yellowish, and cryst, on cooling.
This volatile fat is soluble in hot alcohol, and precipitates partly
on cooling. The weight of material was seventy grammes; it was melted
in the water bath, and filtered through paper in a hot funnel; the
filtered solidified fat was of a light coffee colour, and weighed
fifty-four grammes; in a capillary tube, is soft at 54°, fluid at 62°;
on cooling becomes opaque at 50°. When pressed in paper, the latter is
greased by oleic acid; it contains no ammonia, nor any nitrogen by the
potassium test; the residue on the filter (together with the filter)
was boiled with alcohol, filtered hot on a weighed filter, and washed
with alcohol. This alcoholic solution deposited twelve grammes of fatty
acid, by spontaneous evaporation, during the summer. The crystals
at first deposited were white and warty; a portion of the alcoholic
solution on a glass slide, exhibited with the microscope, white, curved
dendritic forms, arranged stellate; in the capillary tube, they begin
to melt at 53°, are fluid at 62°, and on cooling begin to cloud at
58°, and are opaque at 50°. The residue on the filter weighed about
four grammes, and viewed under the microscope, consisted of membranous
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