On Digestive Proteolysis: Being the Cartwright Lectures for 1894Chittenden, R. H. (Russell Henry)
Science
On Digestive Proteolysis: Being the Cartwright Lectures for 1894
Chittenden, R. H. (Russell Henry)
Digestion; Digestive enzymes; Enzymes
[43] Die Lehre von den chem. Fermenten. Heidelberg, 1882.
[44] Quoted from Gamgee’s Physiological Chemistry of the Animal Body,
vol. 2, p. 7.
[45] Chittenden and Meara. A study of the primary products resulting
from the action of superheated water on coagulated egg-albumin. Journal
of Physiol., vol. 15, p. 501.
We can find many illustrations among chemical phenomena where one
body, even though present in small quantity, acts as a go-between and
makes possible an almost indefinite exchange of matter and energy.
Take as an illustration, the part played by water in determining the
explosion of oxygen and carbon-monoxide gas. Some years ago, Dixon[46]
called attention to the fact that a mixture of these two gases when
perfectly dry would not explode even by contact with red hot platinum
wire. The presence, however, of a small amount of aqueous vapor
would at once cause an explosion to occur. In confirmation of this
observation, Traube[47] has reported that a flame of carbon-monoxide
gas introduced into a perfectly dry atmosphere is at once extinguished.
In a moist atmosphere, on the other hand, the flame will continue to
burn indefinitely, that is as long as the CO gas is supplied. In these
cases, the water, which is so necessary for the appearance of the
reaction, and which furnishes a striking illustration of the action of
a contact or catalytic substance is not purely passive. To be sure,
only a minimal amount is necessary for the combustion of an indefinite
amount of carbonic oxide, but the water enters into the reaction
itself. It is to be noticed that carbonic oxide and water alone, even
at high temperatures, will not react, but in the presence of oxygen
the water is decomposed with formation of hydrogen-peroxide, thus:
CO + 2 H_{2}O + O_{2} = CO(OH)_{2} + H_{2}O_{2}.
[46] Chemical News, vol. 46, p. 151.
[47] Bericht. d. Deutsch. chem. Gesellsch., Band 18, p. 1890.
The hydrogen-peroxide thus formed combines with carbonic oxide to form
carbonic acid, which in turn is decomposed into the anhydride CO_{2},
with regeneration of water, the latter being available for further
action of the same order:
H_{2}O_{2} + CO = CO(OH)_{2}
2 CO(OH)_{2} = 2 CO_{2} + 2 H_{2}O.
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