But a still more important case has next to be considered. Let
us suppose that our drop consists no longer of a single chemical
substance, but contains other substances either in suspension or in
solution. Suppose (as a very simple case) that it be a watery fluid,
exposed to air, and containing droplets of oil: we know that the
specific surface tension of oil in contact with air is much less than
that of water, and it follows that, if the watery surface of our drop
be replaced by an oily surface the specific surface energy of the
system will be notably diminished. Now under these circumstances it is
found that (quite apart from gravity, by which the oil might _float_
to the surface) the oil has a tendency to be _drawn_ to the surface;
and this phenomenon of molecular attraction {279} or “adsorption”
represents the work done, equivalent to the diminished potential energy
of the system[325]. In more general terms, if a liquid (or one or other
of two adjacent liquids) be a chemical mixture, some one constituent
in which, if it entered into or increased in amount in the surface
layer, would have the effect of diminishing its surface tension, then
that constituent will have a tendency to accumulate or concentrate
at the surface: the surface tension may be said, as it were, to
exercise an attraction on this constituent substance, drawing it into
the surface layer, and this tendency will proceed until at a certain
“surface concentration” equilibrium is reached, its opponent being that
osmotic force which tends to keep the substance in uniform solution or
diffusion.
In the complex mixtures which constitute the protoplasm of the living
cell, this phenomenon of “adsorption” has abundant play: for many of
these constituents, such as oils, soaps, albumens, etc. possess the
required property of diminishing surface tension.
Public-domain text, read in full here on John Shaqi.
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