Moreover, the more a substance has the power of lowering the surface
tension of the liquid in which it happens to be dissolved, the more
will it tend to displace another and less effective substance from
the surface layer. Thus we know that protoplasm always contains fats
or oils, not only in visible drops, but also in the finest suspension
or “colloidal solution.” If under any impulse, such for instance as
might arise from the Brownian movement, a droplet of oil be brought
close to the surface, it is at once drawn into that surface, and tends
to spread itself in a thin layer over the whole surface of the cell.
But a soapy surface (for instance) would have in contact with the
surrounding water a surface tension even less than that of the film
of oil: and consequently, if soap be present in the water it will in
turn be adsorbed, and will tend to displace the oil from the surface
pellicle[326]. And this is all as {280} much as to say that the
molecules of the dissolved or suspended substance or substances will
so distribute themselves throughout the drop as to lead towards an
equilibrium, for each small unit of volume, between the superficial and
internal energy; or so, in other words, as to lead towards a reduction
to a minimum of the potential energy of the system. This tendency
to concentration at the surface of any substance within the cell by
which the surface tension tends to be diminished, or _vice versa_,
constitutes, then, the phenomenon of _Adsorption_; and the general
statement by which it is defined is known as the Willard-Gibbs, or
Gibbs-Thomson law[327].
Among the many important physical features or concomitants of this
phenomenon, let us take note at present that we need not conceive of a
strictly superficial distribution of the adsorbed substance, that is
to say of its direct association with the surface layer of molecules
such as we imagined in the case of the electrical charge; but rather of
a progressive tendency to concentrate, more and more, as the surface
is nearly approached. Indeed we may conceive the colloid or gelatinous
precipitate in which, in the case of our protoplasmic cell, the
dissolved substance tends often to be thrown down, to constitute one
boundary layer after another, the general effect being intensified and
multiplied by the repeated addition of these new surfaces.
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