the drop is concerned, then, equilibrium depends on a proper balance
between the energy, per unit area, which is resident in its own two
surfaces, and that which is external thereto: that is to say, if we
call _E__{_bc_} the energy at the surface between the two fluids, and
so on with the other two pairs of surface energies, the condition of
equilibrium, or of maintenance of the drop, is that
_E__{_bc_} < _E__{_ab_} + _E__{_ac_}.
If, on the other hand, the fluid _A_ happens to be oil and the fluid
_B_, water, then the energy _per unit area_ of the water-air surface
is greater than that of the oil-air surface and that of the oil-water
surface together; i.e.
_E__{_wa_} > _E__{_oa_} + _E__{_ow_}.
Here there is no equilibrium, and in order to obtain it the water-air
surface must always tend to decrease and the other two interfacial
surfaces to increase; which is as much as to say that the water tends
to become covered by a spreading film of oil, and the water-air surface
to be abolished. {295}
The surface energy of which we have here spoken is manifested in that
contractile force, or “tension,” of which we have already had so much
to say[341]. In any part of the free water surface, for instance, one
surface particle attracts another surface particle, and the resultant
of these multitudinous attractions is an equilibrium of tension
throughout this particular surface. In the case of our three bodies
in contact with one another, and within a small area very near to
the point of contact, a water particle (for instance) will be pulled
outwards by another water particle; but on the opposite side, so to
speak, there will be no water surface, and no water particle, to
furnish the counterbalancing pull; this counterpull,
[Illustration: Fig. 100.]
[Illustration: Fig. 101.]
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