which is necessary for equilibrium, must therefore be provided by
the tensions existing in the _other two_ surfaces of contact. In
short, if we could imagine a single particle placed at the very point
of contact, it would be drawn upon by three different forces, whose
directions would lie in the three surface planes, and whose magnitude
would be proportional to the specific tensions characteristic of
the two bodies which in each case combine to form the “interfacial”
surface. Now for three forces acting at a point to be in equilibrium,
they must be capable of representation, in magnitude and direction, by
the three sides of a triangle, taken in order, in accordance with the
elementary theorem of the Triangle of Forces. So, if we know the form
of our floating drop (Fig. 100), then by drawing tangents from _O_
(the point of mutual contact), {296} we determine the three angles of
our triangle (Fig. 101), and we therefore know the relative magnitudes
of the three surface tensions, which magnitudes are proportional to
its sides; and conversely, if we know the magnitudes, or relative
magnitudes, of the three sides of the triangle, we also know its
angles, and these determine the form of the section of the drop. It is
scarcely necessary to mention that, since all points on the edge of the
drop are under similar conditions, one with another, the form of the
drop, as we look down upon it from above, must be circular, and the
whole drop must be a solid of revolution.
――――――――――
The principle of the Triangle of Forces is expanded, as follows, by
an old seventeenth-century theorem, called Lami’s Theorem: “_If three
forces acting at a point be in equilibrium, each force is proportional
to the sine of the angle contained between the directions of the other
two._” That is to say
_P_ : _Q_ : _R_ : = sin _QOR_ : sin _POR_ : sin _POQ_.
or _P_/sin _QOR_ = _Q_/sin _ROP_ = _R_/sin _POQ_.
And from this, in turn, we derive the equivalent formulae, by which
each force is expressed in terms of the other two, and of the angle
between them:
_P_^2 = _Q_^2 + _R_^2 + 2_Q_ _R_ cos(_QOR_), etc.
From this and the foregoing, we learn the following important and
useful deductions:
(1) The three forces can only be in equilibrium when any one of them
is less than the sum of the other two: for otherwise, the triangle is
impossible. Now in the case of a drop of olive-oil upon a clean water
surface, the relative magnitudes of the three tensions (at 15° C.) have
been determined as follows:
Water-air surface 75
Oil-air surface 32
Oil-water surface 21
No triangle having sides of these relative magnitudes is possible; and
no such drop therefore can remain in equilibrium. {297}
Public-domain text, read in full here on John Shaqi.
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