Chemical apparatus; Electroplating; Glass blowing and working; Glass coatings; Glass grinding and polishing; Lampwork; Mirrors
The bibliography referring to special points will be given later. The
simplest way of exhibiting the relative resistances of metals is by
means of a diagram published by Dewar and Fleming (loc. cit.), which
is reproduced on a suitable scale on the opposite page. For very
accurate work, in which corrections for the volumes occupied by the
metals at different temperatures are of importance, the reader is
referred to the discussion in the original paper, which will be found
most pleasant reading. From this diagram both the specific resistance
and the temperature coefficient may be deduced with sufficient
accuracy for workshop purposes. In interpreting the diagram the
following notes will be of assistance. The diagram is drawn to a
scale of so-called "platinum temperatures"--that is to say, let R0,
R100, Rt be the resistances of pure platinum at 0 deg., 100 deg., and t deg. C.
respectively, then the platinum temperature pt is defined as
pt = 100 X (Rt-R0)/(R100-R0)
This amounts to making the temperature scale such that the temperature
at any point is proportional to the resistance of platinum at that
point. Consequently on a resistance temperature diagram the straight
line showing the relation between platinum resistance and platinum
temperature will "run out" at the platinum absolute zero, which
coincides more or less with the thermodynamic absolute zero, and also
with the "perfect gas" absolute zero. Platinum temperatures may be
taken for workshop purposes over ordinary ranges as almost coinciding
with air thermometer temperatures. The metals used by Professors
Dewar and Fleming were, with some exceptions, not absolutely pure, but
in general represent the best that can be got by the most refined
process of practical metallurgy. We may note further that the
specific resistance is only correct for a temperature of about 15 deg. C,
since no correction for the expansion or contraction of material has
been applied.
The following notes on alloys suitable for resistance coils will
probably be found sufficient.
Sec. 117. Platinoid.
This substance, discovered by Martino and described by Bottomley
(Phil. Proc. Roy. Soc. 1885), is an alloy of nickel, zinc, copper, and
1 per cent to 2 per cent of tungsten, but I have not been able to
obtain an analysis of its exact composition. It appears to be
difficult to get the tungsten to alloy, and it has to be added to part
of the copper as phosphide of tungsten, in considerably greater
quantity than is finally required. The nickel is added to part of the
copper and the phosphide of tungsten, then the zinc, and then the rest
of the copper. The alloy requires to be remelted several times, and a
good deal of tungsten is lost by oxidation.
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