Chemical apparatus; Electroplating; Glass blowing and working; Glass coatings; Glass grinding and polishing; Lampwork; Mirrors
The alloy is of a fine white colour, and is very little affected by
air--in fact, it is to some extent untarnishable. The specific
resistance will be seen to be about one and a half times greater than
that of German silver, and the temperature coefficient is about 0.021
per cent per degree C. (i.e. about nineteen times less than copper,
and half that of German silver). To all intents and purposes it may
be regarded as German silver with 1 per cent to 2 per cent of
tungsten. It does not appear to have been particularly examined for
secular changes of resistance.
118. German Silver. This material has been exhaustively examined of
late years by Klemencic and by Feussner and St. Lindeck. Everybody
agrees that German silver, as ordinarily used for resistances, and
composed of copper four parts, zinc two parts, nickel one part, is
very ill-fitted for the purpose of making resistance standards. This
is due
(1) to its experiencing a considerable increase in resistance on
winding. Feussner and St. Lindeck found an increase of 1 per cent
when German silver was wound on a core of ten wire diameters.
(2) To the fact that the change goes on, though with gradually
decreasing rate, for months or years;
(3) to the fact that the resistance is permanently changed (increased)
by heating to 40 deg. C. or over. By "artificially ageing" coils of
German silver by heating to 150 deg. C, say for five or six hours, its
permanency is greatly improved, and it becomes fit for ordinary
resistance coils where changes of, say, 1/5000 do not matter.
It is a remarkable property of all nickel alloys containing zinc that
their specific resistance is permanently increased by heating, whereas
alloys which do not contain zinc suffer a change in the opposite
direction. The manufacturers of German silver appear to take very
little care as to the uniformity of the product put on the market;
some so-called German silver is distinctly yellow, while other samples
are bright and white.
It is noted by Price (Measurements of Electrical Resistance, p. 24)
that German silver wire is apt to exhibit great differences of
resistance within quite short lengths. This has been my own
experience as well, and is a great drawback to the use of German
silver in the laboratory, for it makes it useless to measure off
definite lengths of wire with a view to obtaining an approximate
resistance. In England German silver coils are generally soaked in
melted hard paraffin. In Germany, at all events at the Charlottenburg
Institute, according to St. Lindeck--coils are shellac-varnished and
baked. In any case it appears to be essential to thoroughly protect
the metal against atmospheric influence.
Sec. 119. Platinum Silver.
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