Chemical apparatus; Electroplating; Glass blowing and working; Glass coatings; Glass grinding and polishing; Lampwork; Mirrors
Having occasion to require hitherto unapproached lightness and optical
accuracy in such mirrors, I got my assistant to try making them of
fused quartz, slices being cut by a diamond wheel from a rod of that
material. Chips of natural quartz were also obtained from broken
"pebble" spectacles, and these were worked at the same time. The
resulting mirrors were certainly superior to the best we could make
from glass, but the labour of grinding was greater, and the labour of
polishing less, than in the latter case. The pebble fragments gave
practically as good mirrors as the fused slices. For the future it
will be better always to make galvanometer mirrors from quartz
crystals. These may be easily sliced, as will be described in Sec. 74.
The slices are dressed on a grindstone according to instructions
already given for small lenses.
The silvering of these mirrors is a point of great importance. After
trying nearly every formula published, we have settled down to the
following.
A solution of pure crystallised nitrate of silver in distilled water
is made up to a strength of 125 grams of the salt per litre. This
forms the stock solution and is kept in a dark bottle.
Let the volume of silvering liquor required in any operation be
denoted by 4 v. The liquor is prepared as follows:
I. Measure out a volume v of the stock solution of silver nitrate,
and calculate the weight of salt which it contains; let this be w.
In another vessel dissolve pure Rochelle salt to the amount of 2.6 w,
and make up the solution to the volume v. These two solutions are to
be mixed together at a temperature of 55 deg. C, the vessels with their
contents being heated to this temperature on the water bath. After
mixing the liquids the temperature is to be kept approximately
constant for five minutes, after which the liquor may be cooled. The
white precipitate which first forms will become gray or black and very
dense as the liquid cools. If it does not, the liquor must be
reheated to 55 deg. C, and kept at that temperature for a few minutes and
then again allowed to cool. The solution is in good order when all
the precipitate is dense and gray or black and the liquor clear. The
blacker and denser the precipitate the better is the solution. The
liquor is decanted and filtered from the precipitate and brought up to
the volume 2 v by addition of some of the wash water.
II. Measure out a volume 0.118 v of the stock solution into a
separate vessel, and add to it a 5 per cent solution of ammonium
hydrate, with proper precautions, so that the precipitate at first
formed is all but redissolved after vigorous shaking. It is very
important that this condition should be exactly attained. Therefore
add the latter part of the ammonia very carefully. Make up the volume
to 2 v.
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