Chemical apparatus; Electroplating; Glass blowing and working; Glass coatings; Glass grinding and polishing; Lampwork; Mirrors
Mix the solutions I. and II. in a separate vessel and pour the
mixture into the depositing vessel. The surface to be silvered should
face downwards, and lie just beneath the free surface of the liquid.
Bubbles must of course be removed.
The silver deposit obtained in this manner is exceedingly white and,
bright on the surface next to the glass, but the back is mat and
requires polishing.
The detail of the process described above was worked out in my
laboratory by Mr. A. Pollock, to whom my thanks are due.
This process gives good deposits when the solutions are freshly
prepared, but the ammonia solution will not keep; The surfaces to be
silvered require to be absolutely clean. The process is assisted by a
summer temperature, say 70 deg. Fahr, and possibly by the action of
light. Six or seven hours at least are required for a good deposit; a
good plan is to leave the mirrors in the bath all night. On removal
from the bath the mirrors require to be well washed, and allowed to
dry thoroughly in sun heat for several hours before they are touched.
Care should be taken not to pull the mirrors out of shape when they
are mounted for the bath. A single drop of varnish or paint (a mere
speck) on the centre will suffice to hold them. The back of the
deposit requires to be varnished or painted as a rule to preserve the
silver. All paints and varnishes thus applied tend to spoil the
figure by expanding or contracting. On the whole, I think boiled
linseed oil and white or red lead--white or red paint in fact--is
less deleterious than other things I have tried. Shellac varnish is
the worst.
Of course, the best mirror can be easily spoiled by bad mounting. I
have tried a great number of methods and can recommend as fairly
successful the following:- A little pure white lead, i.e. bought as
pure as a chemical--not as a paint--is mixed with an equal quantity
of red lead and made into a paste with a little linseed oil. I say a
paste, not putty. A trace of this is then worked on to the back of
the mirror at the centre as nearly as may be, and to this is attached
the support. The only objection to this is that nearly a week is
required for the paste to set. If people must use shellac let it be
remembered that it will go on changing its shape for months after it
has cooled (whether it has been dissolved in alcohol or not).
Sec. 66. Preparation of Large Mirrors or Lenses for Telescopes.
Public-domain text, read in full here on John Shaqi.
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